#PDB cf residue atom bb_p bb_s bb_f chi_p chi_s HB-D HB-I REF pred #--------------------------------------------------------------------------------------------- 1vdj h VAL 132 N 0.00 0.32 -1.92 3.15 2.07 -2.05 -1.32 116.25 116.50 1vdj h VAL 132 Ca 0.00 -0.30 0.56 0.00 0.82 0.00 0.00 66.70 67.78 1vdj h VAL 132 Cb 0.00 0.41 -0.08 0.00 -1.52 0.00 0.00 31.29 30.10 1vdj h VAL 132 CO 0.00 0.04 1.38 -0.46 0.02 0.00 0.00 177.57 178.54 1vdj n ASN 133 N -5.35 0.00 -0.04 0.57 6.94 -1.26 0.01 115.26 116.13 1vdj n ASN 133 Ca -0.12 0.97 -0.00 0.00 -0.02 0.00 0.00 54.58 55.41 1vdj n ASN 133 Cb 0.34 -0.49 -0.00 0.00 -2.36 0.00 0.00 39.78 37.28 1vdj n ASN 133 CO 0.00 0.00 0.00 0.24 -1.03 0.00 0.00 177.26 176.47 1vdj h MET 134 N 0.00 0.00 -1.20 -3.83 2.86 -1.86 -1.19 114.93 109.71 1vdj h MET 134 Ca 0.92 0.00 0.41 0.00 -2.06 0.00 0.00 59.70 58.96 1vdj h MET 134 Cb 3.67 0.00 -0.14 0.00 0.06 0.00 0.00 31.60 35.19 1vdj h MET 134 CO -0.02 0.00 0.75 -0.44 1.06 0.00 0.00 176.91 178.26 1vdj h ASP 135 N -0.87 0.31 0.06 1.22 5.19 0.72 0.55 116.42 123.59 1vdj h ASP 135 Ca 0.00 0.16 -0.00 0.00 -0.62 0.00 0.00 57.03 56.57 1vdj h ASP 135 Cb 0.02 0.15 0.00 0.00 0.18 0.00 0.00 39.33 39.67 1vdj h ASP 135 CO 0.00 -0.21 -0.03 0.25 -3.12 0.00 0.00 179.24 176.13 1vdj h LEU 136 N 0.12 -0.06 -0.93 1.55 5.85 -0.92 -0.72 115.31 120.20 1vdj h LEU 136 Ca 0.80 -0.58 0.16 0.00 0.84 0.00 0.00 57.88 59.10 1vdj h LEU 136 Cb 2.33 0.02 -0.16 0.00 0.37 0.00 0.00 40.66 43.22 1vdj h LEU 136 CO -0.51 0.65 -0.32 -1.14 -0.34 0.00 0.00 178.44 176.78 1vdj n ARG 137 N -4.78 -0.17 -0.03 1.25 0.63 0.18 0.19 116.66 113.92 1vdj n ARG 137 Ca -0.08 1.43 -0.14 0.00 -0.92 0.00 0.00 57.85 58.14 1vdj n ARG 137 Cb 0.31 -2.13 -0.09 0.00 0.45 0.00 0.00 32.46 31.00 1vdj n ARG 137 CO 0.00 0.00 0.00 0.00 -2.51 0.00 0.00 177.63 175.12 1vdj h ALA 138 N 1.47 0.10 -1.75 5.13 0.00 -1.25 0.25 119.26 123.20 1vdj h ALA 138 Ca 0.36 -0.37 0.54 0.00 0.00 0.00 0.00 54.91 55.45 1vdj h ALA 138 Cb 0.59 -0.01 -0.10 0.00 0.00 0.00 0.00 17.79 18.27 1vdj h ALA 138 CO -0.93 0.02 1.22 -1.71 0.00 0.00 0.00 179.25 177.86 1vdj n ASN 139 N -4.59 0.08 -0.04 0.00 5.15 0.13 0.15 115.26 116.14 1vdj n ASN 139 Ca -0.08 1.14 -0.03 0.00 -0.60 0.00 0.00 54.58 55.01 1vdj n ASN 139 Cb 0.40 -0.57 -0.01 0.00 -0.53 0.00 0.00 39.78 39.07 1vdj n ASN 139 CO 0.00 0.00 0.00 -0.11 1.40 0.00 0.00 177.26 178.55 1vdj n LEU 140 N -4.22 0.79 -0.40 1.20 7.94 0.25 -4.57 117.00 117.98 1vdj n LEU 140 Ca 0.43 0.21 -0.05 0.00 -1.11 0.00 0.00 56.01 55.49 1vdj n LEU 140 Cb 1.85 -0.61 -0.01 0.00 0.53 0.00 0.00 43.42 45.17 1vdj n LEU 140 CO 0.35 -0.43 0.54 1.17 -1.11 0.00 0.00 177.39 177.91 1vdj n LYS 141 N -3.29 -0.31 -0.70 1.96 3.00 0.85 -4.57 118.16 115.10 1vdj n LYS 141 Ca -0.05 1.53 -0.23 0.00 -0.00 0.00 0.00 58.31 59.55 1vdj n LYS 141 Cb 0.19 -2.26 -0.01 0.00 0.00 0.00 0.00 35.03 32.95 1vdj n LYS 141 CO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 177.40 177.40 1vdj n GLN 142 N -5.39 0.00 -3.18 1.64 10.64 0.40 -3.21 117.38 118.29 1vdj n GLN 142 Ca 0.07 0.00 -0.00 0.00 -1.83 0.00 0.00 57.00 55.24 1vdj n GLN 142 Cb 0.35 -0.53 -0.00 0.00 -0.86 0.00 0.00 30.24 29.20 1vdj n GLN 142 CO 0.00 0.00 0.00 1.55 -1.83 0.00 0.00 177.06 176.78 1vdj n VAL 143 N -0.34 -2.16 -3.62 -0.39 3.14 -1.26 -4.97 118.33 108.73 1vdj n VAL 143 Ca 0.07 0.51 -0.27 0.00 -2.96 0.00 0.00 64.34 61.69 1vdj n VAL 143 Cb 0.18 -3.06 -0.16 0.00 -1.06 0.00 0.00 33.84 29.74 1vdj n VAL 143 CO 0.00 0.00 0.00 -1.59 -6.46 0.00 0.00 176.83 168.78 1vdj s LYS 144 N -0.99 0.22 0.01 1.45 -2.85 -0.88 -5.05 119.74 111.66 1vdj s LYS 144 Ca -0.00 -0.28 -0.08 0.00 -1.00 0.00 0.00 55.97 54.61 1vdj s LYS 144 Cb 0.00 -1.74 -0.00 0.00 -2.06 0.00 0.00 37.83 34.03 1vdj s LYS 144 CO 0.01 -0.76 0.14 -1.59 0.10 0.00 0.00 175.35 173.26 1vdj s LYS 145 N 2.06 0.54 0.00 1.78 0.00 -1.26 0.37 119.74 123.23 1vdj s LYS 145 Ca 0.03 -0.49 0.02 0.00 0.00 0.00 0.00 55.97 55.53 1vdj s LYS 145 Cb -0.16 0.22 0.01 0.00 0.00 0.00 0.00 37.83 37.90 1vdj s LYS 145 CO -0.16 -0.14 0.52 0.39 0.00 0.00 0.00 175.35 175.97 1vdj n GLU 146 N 1.20 0.08 -0.80 1.78 -0.58 -0.58 -5.01 120.64 116.73 1vdj n GLU 146 Ca -0.21 -0.57 0.04 0.00 -0.42 0.00 0.00 57.16 56.00 1vdj n GLU 146 Cb 0.57 -0.99 -0.02 0.00 -0.57 0.00 0.00 31.44 30.42 1vdj n GLU 146 CO 0.00 0.00 0.00 -0.25 -0.48 0.00 0.00 177.13 176.40 1vdj n ASP 147 N -0.00 -4.33 -1.87 1.62 9.92 -1.17 -4.99 116.55 115.73 1vdj n ASP 147 Ca 0.01 0.90 -0.00 0.00 -0.53 0.00 0.00 54.79 55.17 1vdj n ASP 147 Cb 0.05 -2.38 0.00 0.00 -0.64 0.00 0.00 41.12 38.16 1vdj n ASP 147 CO 0.00 0.00 0.00 0.41 0.13 0.00 0.00 177.20 177.74 1vdj n THR 148 N -2.56 -3.14 -3.39 -3.53 -1.04 -1.26 -4.44 114.28 94.92 1vdj n THR 148 Ca -0.02 -0.09 -0.11 0.00 -2.04 0.00 0.00 64.05 61.79 1vdj n THR 148 Cb 0.30 -4.25 0.00 0.00 -1.82 0.00 0.00 70.33 64.56 1vdj n THR 148 CO 0.00 0.00 0.00 -0.62 -0.64 0.00 0.00 175.07 173.81 1vdj n GLU 149 N -1.27 -1.43 0.00 -2.82 1.02 -1.26 -4.98 120.64 109.90 1vdj n GLU 149 Ca -0.00 1.17 0.00 0.00 -0.02 0.00 0.00 57.16 58.31 1vdj n GLU 149 Cb 0.50 -4.19 0.00 0.00 -0.02 0.00 0.00 31.44 27.73 1vdj n GLU 149 CO 0.00 0.00 0.00 0.36 1.18 0.00 0.00 177.13 178.67 1vdj n LYS 150 N -2.15 0.00 -4.07 3.49 2.85 -1.26 -5.07 118.16 111.95 1vdj n LYS 150 Ca -0.15 0.00 -0.13 0.00 -1.05 0.00 0.00 58.31 56.98 1vdj n LYS 150 Cb 0.59 0.00 -0.11 0.00 -0.65 0.00 0.00 35.03 34.86 1vdj n LYS 150 CO 0.00 0.00 0.00 -1.21 -0.05 0.00 0.00 177.40 176.14 1vdj s GLU 151 N 0.00 0.55 -0.14 -1.58 8.01 -1.26 -1.53 118.70 122.75 1vdj s GLU 151 Ca 0.00 -0.79 -0.03 0.00 0.01 0.00 0.00 54.97 54.17 1vdj s GLU 151 Cb 0.00 -0.30 0.05 0.00 -4.31 0.00 0.00 34.13 29.57 1vdj s GLU 151 CO 0.00 0.05 0.03 0.15 0.01 0.00 0.00 175.26 175.51 1vdj s LYS 152 N -1.68 0.49 -0.34 1.61 1.02 0.16 -4.96 119.74 116.03 1vdj s LYS 152 Ca -0.09 -0.13 -0.09 0.00 0.02 0.00 0.00 55.97 55.68 1vdj s LYS 152 Cb -0.09 -1.56 0.02 0.00 -0.52 0.00 0.00 37.83 35.68 1vdj s LYS 152 CO 0.00 -0.51 0.16 0.16 -0.92 0.00 0.00 175.35 174.24 1vdj s ASP 153 N 1.97 5.53 0.00 2.83 1.47 -1.26 -2.07 116.67 125.14 1vdj s ASP 153 Ca 0.02 -0.91 0.00 0.00 1.18 0.00 0.00 52.55 52.84 1vdj s ASP 153 Cb -0.15 -1.97 0.00 0.00 -0.34 0.00 0.00 42.92 40.46 1vdj s ASP 153 CO -0.07 -0.31 0.00 0.00 0.68 0.00 0.00 175.17 175.47 1vdj n LEU 154 N 4.94 0.00 0.10 2.11 -0.00 -1.26 -4.84 117.00 118.04 1vdj n LEU 154 Ca -0.13 0.00 -0.14 0.00 -0.00 0.00 0.00 56.01 55.74 1vdj n LEU 154 Cb 0.46 0.00 -0.12 0.00 -0.00 0.00 0.00 43.42 43.76 1vdj n LEU 154 CO 0.34 -0.38 0.01 0.08 -0.00 0.00 0.00 177.39 177.45 1vdj h ARG 155 N 0.00 0.25 -0.34 1.47 0.11 -2.01 -3.31 114.38 110.56 1vdj h ARG 155 Ca 0.00 -0.40 0.07 0.00 0.10 0.00 0.00 59.98 59.75 1vdj h ARG 155 Cb 0.00 0.14 -0.08 0.00 1.11 0.00 0.00 29.97 31.14 1vdj h ARG 155 CO 0.00 1.17 -0.37 0.22 0.10 0.00 0.00 179.97 181.09 1vdj h ASP 156 N 0.08 -1.22 0.00 0.08 3.58 -2.03 -3.39 116.42 113.52 1vdj h ASP 156 Ca -0.11 0.19 0.00 0.00 0.42 0.00 0.00 57.03 57.53 1vdj h ASP 156 Cb 1.89 0.54 0.00 0.00 1.72 0.00 0.00 39.33 43.48 1vdj h ASP 156 CO 0.19 -0.36 0.00 0.55 -2.88 0.00 0.00 179.24 176.74 1vdj n VAL 157 N -5.42 0.00 0.00 2.25 3.14 -1.25 -4.32 118.33 112.73 1vdj n VAL 157 Ca -0.01 0.00 0.00 0.00 -2.96 0.00 0.00 64.34 61.37 1vdj n VAL 157 Cb 0.35 0.00 0.00 0.00 -1.06 0.00 0.00 33.84 33.13 1vdj n VAL 157 CO 0.00 0.00 0.00 0.61 -6.46 0.00 0.00 176.83 170.98 1vdj n GLY 158 N 0.00 0.39 0.06 7.55 0.00 -1.26 0.77 105.19 112.69 1vdj n GLY 158 Ca 0.00 0.30 -0.02 0.00 0.00 0.00 0.00 46.02 46.30 1vdj n GLY 158 CO 0.00 0.00 0.00 -1.80 0.00 0.00 0.00 173.32 171.52 1vdj h ASP 159 N 0.00 0.00 -0.84 1.61 3.58 -1.99 -2.61 116.42 116.17 1vdj h ASP 159 Ca 0.00 -0.05 0.16 0.00 0.42 0.00 0.00 57.03 57.56 1vdj h ASP 159 Cb 0.00 0.00 -0.15 0.00 1.72 0.00 0.00 39.33 40.90 1vdj h ASP 159 CO 0.00 0.61 -0.24 1.87 -2.88 0.00 0.00 179.24 178.60 1vdj n TRP 160 N -4.72 0.23 0.04 0.28 -0.00 0.23 -0.83 117.44 112.67 1vdj n TRP 160 Ca -0.03 1.03 -0.02 0.00 -0.00 0.00 0.00 57.50 58.49 1vdj n TRP 160 Cb 0.10 -0.95 -0.01 0.00 -0.00 0.00 0.00 31.31 30.46 1vdj n TRP 160 CO 0.00 0.00 0.00 -0.09 -0.00 0.00 0.00 177.69 177.60 1vdj h ARG 161 N 0.00 -0.11 -0.24 5.87 2.43 -0.64 -2.28 114.38 119.42 1vdj h ARG 161 Ca 0.38 0.01 0.07 0.00 -0.81 0.00 0.00 59.98 59.63 1vdj h ARG 161 Cb 0.59 0.02 -0.04 0.00 -0.42 0.00 0.00 29.97 30.12 1vdj h ARG 161 CO -0.86 -0.07 0.02 0.36 -1.51 0.00 0.00 179.97 177.91 1vdj n LYS 162 N -2.32 -0.02 0.00 0.20 -0.00 -0.01 0.25 118.16 116.26 1vdj n LYS 162 Ca -0.01 0.35 0.00 0.00 -0.00 0.00 0.00 58.31 58.65 1vdj n LYS 162 Cb 0.04 -0.57 0.00 0.00 -0.00 0.00 0.00 35.03 34.50 1vdj n LYS 162 CO 0.00 0.00 0.00 0.09 0.00 0.00 0.00 177.40 177.49 1vdj n ASN 163 N -4.01 0.00 0.29 -5.58 3.02 -0.42 -1.82 115.26 106.74 1vdj n ASN 163 Ca 0.06 0.62 -0.18 0.00 -0.03 0.00 0.00 54.58 55.05 1vdj n ASN 163 Cb 0.20 -0.27 -0.10 0.00 -0.61 0.00 0.00 39.78 39.01 1vdj n ASN 163 CO 0.00 0.00 0.00 0.16 -2.62 0.00 0.00 177.26 174.80 1vdj h ILE 164 N 0.00 0.00 -0.81 2.41 -0.00 0.11 0.05 117.51 119.27 1vdj h ILE 164 Ca 0.00 0.00 0.23 0.00 -0.00 0.00 0.00 64.86 65.09 1vdj h ILE 164 Cb 0.00 0.00 -0.15 0.00 -0.00 0.00 0.00 36.82 36.67 1vdj h ILE 164 CO 0.00 0.00 0.04 1.21 -0.00 0.00 0.00 178.15 179.40 1vdj n GLU 165 N -5.52 -0.06 0.00 0.16 4.07 0.68 0.30 120.64 120.26 1vdj n GLU 165 Ca -0.12 1.20 0.00 0.00 -0.06 0.00 0.00 57.16 58.18 1vdj n GLU 165 Cb 0.46 -1.92 0.00 0.00 -0.06 0.00 0.00 31.44 29.92 1vdj n GLU 165 CO 0.00 0.00 0.00 -1.91 -0.06 0.00 0.00 177.13 175.16 1vdj n GLU 166 N -5.13 0.00 -0.39 5.31 4.07 -0.72 -3.65 120.64 120.14 1vdj n GLU 166 Ca 0.20 0.00 0.35 0.00 -0.06 0.00 0.00 57.16 57.64 1vdj n GLU 166 Cb 0.64 -0.72 0.60 0.00 -0.06 0.00 0.00 31.44 31.90 1vdj n GLU 166 CO 0.00 0.00 0.00 0.36 -0.06 0.00 0.00 177.13 177.43 1vdj n LYS 167 N -0.49 -0.04 -2.03 5.31 2.85 -0.08 -4.26 118.16 119.42 1vdj n LYS 167 Ca 0.00 1.19 -0.39 0.00 -1.05 0.00 0.00 58.31 58.05 1vdj n LYS 167 Cb 0.00 -2.27 -0.00 0.00 -0.65 0.00 0.00 35.03 32.11 1vdj n LYS 167 CO 0.00 0.00 0.00 -1.12 -0.05 0.00 0.00 177.40 176.23 1vdj s SER 168 N -4.38 6.22 0.00 -5.58 0.01 0.87 -1.88 113.70 108.96 1vdj s SER 168 Ca -0.07 2.67 0.00 0.00 1.31 0.00 0.00 55.95 59.86 1vdj s SER 168 Cb 0.29 -2.64 0.00 0.00 0.21 0.00 0.00 66.02 63.88 1vdj s SER 168 CO 0.74 -0.92 0.00 0.61 0.41 0.00 0.00 173.24 174.08 1vdj n GLY 169 N 0.65 2.06 0.31 3.44 0.00 -1.26 -4.55 105.19 105.84 1vdj n GLY 169 Ca 0.04 -0.27 -0.10 0.00 0.00 0.00 0.00 46.02 45.70 1vdj n GLY 169 CO 0.00 0.00 0.00 -0.33 0.00 0.00 0.00 173.32 172.99 1vdj h MET 170 N 0.00 -0.35 -0.82 1.61 2.86 -1.74 0.32 114.93 116.81 1vdj h MET 170 Ca 0.00 0.02 0.19 0.00 -2.06 0.00 0.00 59.70 57.85 1vdj h MET 170 Cb 0.00 0.08 -0.12 0.00 0.06 0.00 0.00 31.60 31.62 1vdj h MET 170 CO 0.00 -0.23 0.26 1.49 1.06 0.00 0.00 176.91 179.49 1vdj h GLU 171 N -0.36 0.30 0.00 1.72 4.81 -1.61 0.20 114.58 119.65 1vdj h GLU 171 Ca 0.03 -0.02 0.00 0.00 -0.13 0.00 0.00 59.36 59.24 1vdj h GLU 171 Cb 0.44 -0.07 0.00 0.00 0.63 0.00 0.00 28.75 29.75 1vdj h GLU 171 CO -0.32 0.20 0.00 0.41 -0.73 0.00 0.00 179.01 178.57 1vdj n GLY 172 N -1.35 -2.57 0.57 1.92 0.00 -0.31 -0.42 105.19 103.02 1vdj n GLY 172 Ca 0.18 0.03 0.41 0.00 0.00 0.00 0.00 46.02 46.64 1vdj n GLY 172 CO 0.00 0.00 0.00 3.21 0.00 0.00 0.00 173.32 176.53 1vdj h ARG 173 N 0.00 0.05 -0.24 1.61 3.08 -0.14 1.60 114.38 120.35 1vdj h ARG 173 Ca 0.00 -0.00 -0.08 0.00 0.07 0.00 0.00 59.98 59.97 1vdj h ARG 173 Cb 0.00 -0.01 -0.01 0.00 0.08 0.00 0.00 29.97 30.03 1vdj h ARG 173 CO 0.00 0.03 -0.16 0.87 -1.07 0.00 0.00 179.97 179.64 1vdj h LYS 174 N 0.05 0.53 0.00 0.04 1.79 -0.26 -1.27 116.57 117.45 1vdj h LYS 174 Ca 0.75 -0.25 0.00 0.00 -2.18 0.00 0.00 60.65 58.97 1vdj h LYS 174 Cb 2.79 -0.00 0.00 0.00 -1.58 0.00 0.00 32.23 33.44 1vdj h LYS 174 CO -0.12 0.82 0.00 1.63 -1.08 0.00 0.00 179.45 180.70 1vdj n LYS 175 N -4.45 0.22 -0.08 3.15 4.01 0.50 -1.16 118.16 120.36 1vdj n LYS 175 Ca -0.04 0.04 -0.12 0.00 -0.51 0.00 0.00 58.31 57.69 1vdj n LYS 175 Cb 0.38 -1.50 -0.08 0.00 -0.51 0.00 0.00 35.03 33.32 1vdj n LYS 175 CO 0.00 0.00 0.00 1.98 -1.11 0.00 0.00 177.40 178.27 1vdj h MET 176 N 0.00 0.00 0.04 1.97 1.85 0.49 -3.38 114.93 115.89 1vdj h MET 176 Ca 0.00 0.00 -0.25 0.00 -0.61 0.00 0.00 59.70 58.84 1vdj h MET 176 Cb 0.33 0.00 0.01 0.00 0.43 0.00 0.00 31.60 32.37 1vdj h MET 176 CO 0.00 0.60 -1.06 0.27 -0.40 0.00 0.00 176.91 176.32 1vdj h PHE 177 N -1.00 0.78 -4.76 1.39 -0.00 -1.29 -3.49 116.94 108.57 1vdj h PHE 177 Ca -0.10 -0.45 0.00 0.00 -0.00 0.00 0.00 57.97 57.42 1vdj h PHE 177 Cb 0.78 -0.08 0.00 0.00 -0.00 0.00 0.00 35.95 36.66 1vdj h PHE 177 CO 0.07 1.29 -0.64 -1.91 -0.00 0.00 0.00 178.31 177.12 1vdj n GLU 178 N -3.76 -0.24 0.00 6.09 2.13 -0.31 -4.90 120.64 119.65 1vdj n GLU 178 Ca -0.09 0.57 0.00 0.00 0.66 0.00 0.00 57.16 58.30 1vdj n GLU 178 Cb 0.89 -0.68 0.00 0.00 0.27 0.00 0.00 31.44 31.93 1vdj n GLU 178 CO 0.00 0.00 0.00 0.00 -0.41 0.00 0.00 177.13 176.72 1vdj n ALA 179 N 1.15 2.02 -3.05 4.31 0.00 -1.26 -5.03 120.51 118.64 1vdj n ALA 179 Ca 0.00 0.00 -0.45 0.00 0.00 0.00 0.00 53.44 52.99 1vdj n ALA 179 Cb 0.32 0.00 -0.05 0.00 0.00 0.00 0.00 19.45 19.72 1vdj n ALA 179 CO 0.00 0.00 0.00 0.20 0.00 0.00 0.00 177.50 177.70 1vdj s GLY 180 N -3.70 1.77 -0.04 0.00 0.00 -1.26 -5.01 107.32 99.08 1vdj s GLY 180 Ca 0.00 -2.15 -0.01 0.00 0.00 0.00 0.00 44.72 42.56 1vdj s GLY 180 CO 0.00 1.57 0.02 1.85 0.00 0.00 0.00 173.10 176.55 1vdj s GLU 181 N 2.70 0.15 0.00 2.90 2.12 -1.26 -5.16 118.70 120.15 1vdj s GLU 181 Ca 0.12 0.19 0.24 0.00 0.36 0.00 0.00 54.97 55.89 1vdj s GLU 181 Cb -0.23 -0.49 0.27 0.00 0.26 0.00 0.00 34.13 33.94 1vdj s GLU 181 CO 0.07 -0.22 1.31 0.45 -0.54 0.00 0.00 175.26 176.33