============================================================================= SHIFTS, version 4.1 [X.-P. Xu and D.A. Case, Mar. 2002] ============================================================================= shifts will be computed for atoms matching ::H* found 6 rings ring int. center anis. iso. HIS 8 0.900 8.968 4.456 -4.211 -99.200 -91.000 HIS 13 0.900 7.867 -3.409 -4.186 -99.200 -91.000 TRP 22 1.040 0.206 -2.259 -2.096 -99.200 -91.000 TRP6 22 1.020 -0.673 -3.230 -4.100 -99.200 -91.000 HIS 31 0.900 -6.980 12.872 -5.536 -99.200 -91.000 PHE 33 1.000 1.035 8.121 2.176 -99.200 -91.000 ============================================================================= Atom RingCur El P_anis Const RC pred Obs ============================================================================= 1zwbA3 VAL 1 HA 0.00 -0.06 0.21 -0.75 4.13 3.53 1zwbA3 VAL 1 HB -0.00 -0.00 0.02 -0.04 2.12 2.09 1zwbA3 VAL 1 HG13 -0.00 -0.00 0.03 -0.04 0.97 0.96 1zwbA3 VAL 1 HG23 0.00 -0.01 0.08 -0.04 0.95 0.98 1zwbA3 SER 2 H 0.00 0.17 0.06 -0.55 8.46 8.14 1zwbA3 SER 2 HA 0.01 0.11 0.52 -0.75 4.49 4.37 1zwbA3 SER 2 HB2 0.01 0.17 -0.28 -0.04 3.95 3.81 1zwbA3 SER 2 HB3 0.01 -0.00 0.07 -0.04 3.93 3.96 1zwbA3 GLU 3 H 0.01 0.14 0.15 -0.55 8.60 8.36 1zwbA3 GLU 3 HA 0.02 -0.01 0.33 -0.75 4.29 3.87 1zwbA3 GLU 3 HB2 0.01 0.22 0.12 -0.04 2.09 2.40 1zwbA3 GLU 3 HB3 0.01 -0.00 0.20 -0.04 1.99 2.16 1zwbA3 GLU 3 HG2 0.01 0.03 -0.01 -0.04 2.34 2.33 1zwbA3 GLU 3 HG3 0.01 -0.05 -0.02 -0.04 2.34 2.24 1zwbA3 ILE 4 H 0.02 0.11 -0.19 -0.55 8.25 7.64 1zwbA3 ILE 4 HA 0.08 0.06 0.49 -0.75 4.18 4.06 1zwbA3 ILE 4 HB 0.01 0.22 -0.22 -0.04 1.89 1.87 1zwbA3 ILE 4 HG12 -0.01 -0.11 0.12 -0.04 1.49 1.45 1zwbA3 ILE 4 HG13 -0.02 0.06 0.00 -0.04 1.21 1.21 1zwbA3 ILE 4 HG23 -0.00 0.02 -0.21 -0.04 0.93 0.70 1zwbA3 ILE 4 HD13 -0.07 0.00 -0.18 -0.04 0.88 0.59 1zwbA3 GLN 5 H 0.09 0.22 0.05 -0.55 8.47 8.29 1zwbA3 GLN 5 HA -0.03 0.08 0.37 -0.75 4.36 4.02 1zwbA3 GLN 5 HB2 -0.02 0.04 -0.35 -0.04 2.15 1.79 1zwbA3 GLN 5 HB3 -0.00 0.06 0.16 -0.04 2.02 2.19 1zwbA3 GLN 5 HG2 -0.02 0.05 -0.02 -0.04 2.40 2.37 1zwbA3 GLN 5 HG3 -0.03 -0.01 0.02 -0.04 2.39 2.33 1zwbA3 GLN 5 HE21 -0.04 0.03 -0.05 -0.04 6.97 6.87 1zwbA3 GLN 5 HE22 -0.07 0.02 -0.03 -0.04 7.69 7.56 1zwbA3 LEU 6 H 0.03 0.60 -0.22 -0.55 8.37 8.23 1zwbA3 LEU 6 HA 0.01 0.12 0.34 -0.75 4.35 4.06 1zwbA3 LEU 6 HB2 0.02 0.08 0.12 -0.04 1.64 1.82 1zwbA3 LEU 6 HB3 0.02 -0.08 0.01 -0.04 1.64 1.55 1zwbA3 LEU 6 HG 0.01 0.03 0.01 -0.04 1.64 1.65 1zwbA3 LEU 6 HD13 0.01 0.01 0.01 -0.04 0.93 0.92 1zwbA3 LEU 6 HD23 0.02 0.00 -0.22 -0.04 0.89 0.65 1zwbA3 MET 7 H 0.05 0.04 -0.34 -0.55 8.47 7.66 1zwbA3 MET 7 HA 0.01 0.09 0.28 -0.75 4.52 4.14 1zwbA3 MET 7 HB2 0.03 -0.09 -0.08 -0.04 2.15 1.97 1zwbA3 MET 7 HB3 -0.06 0.11 -0.11 -0.04 2.03 1.93 1zwbA3 MET 7 HG2 0.02 0.08 -0.04 -0.04 2.63 2.65 1zwbA3 MET 7 HG3 0.02 -0.08 -0.07 -0.04 2.56 2.39 1zwbA3 MET 7 HE3 0.02 0.00 -0.00 -0.04 2.10 2.08 1zwbA3 HIS 8 H 0.16 -0.08 -0.48 -0.55 8.41 7.46 1zwbA3 HIS 8 HA -0.06 0.11 0.33 -0.75 4.63 4.26 1zwbA3 HIS 8 HB2 -0.09 0.00 0.11 -0.04 3.26 3.25 1zwbA3 HIS 8 HB3 -0.12 0.06 -0.03 -0.04 3.20 3.07 1zwbA3 HIS 8 HD2 -0.03 -0.26 0.00 -0.04 6.97 6.63 1zwbA3 HIS 8 HE1 -0.01 0.04 -0.01 -0.04 7.75 7.73 1zwbA3 ASN 9 H -0.05 0.57 -0.14 -0.55 8.53 8.37 1zwbA3 ASN 9 HA -0.72 0.04 0.42 -0.75 4.76 3.73 1zwbA3 ASN 9 HB2 -0.03 0.04 0.10 -0.04 2.88 2.95 1zwbA3 ASN 9 HB3 0.02 -0.05 0.06 -0.04 2.79 2.77 1zwbA3 ASN 9 HD21 -0.03 0.30 0.02 -0.04 7.03 7.27 1zwbA3 ASN 9 HD22 -0.02 -0.05 -0.03 -0.04 7.74 7.60 1zwbA3 LEU 10 H -0.04 0.17 -0.70 -0.55 8.37 7.25 1zwbA3 LEU 10 HA 0.05 0.06 0.43 -0.75 4.35 4.14 1zwbA3 LEU 10 HB2 0.02 0.14 0.10 -0.04 1.64 1.86 1zwbA3 LEU 10 HB3 0.05 -0.12 0.10 -0.04 1.64 1.63 1zwbA3 LEU 10 HG 0.03 -0.03 -0.01 -0.04 1.64 1.59 1zwbA3 LEU 10 HD13 0.03 -0.02 0.04 -0.04 0.93 0.94 1zwbA3 LEU 10 HD23 0.02 0.03 -0.09 -0.04 0.89 0.82 1zwbA3 GLY 11 H 0.06 0.14 0.03 -0.55 8.43 8.11 1zwbA3 GLY 11 HA2 0.02 0.04 0.47 -0.51 4.01 4.03 1zwbA3 GLY 11 HA3 0.08 0.01 0.37 -0.51 4.01 3.95 1zwbA3 LYS 12 H 0.21 0.71 -0.36 -0.55 8.42 8.42 1zwbA3 LYS 12 HA 0.57 0.09 0.63 -0.75 4.32 4.85 1zwbA3 LYS 12 HB2 0.05 0.20 -0.10 -0.04 1.87 1.98 1zwbA3 LYS 12 HB3 0.07 -0.05 0.11 -0.04 1.79 1.88 1zwbA3 LYS 12 HG2 0.20 0.12 -0.22 -0.04 1.46 1.51 1zwbA3 LYS 12 HG3 0.06 -0.01 -0.15 -0.04 1.46 1.32 1zwbA3 LYS 12 HD2 0.15 -0.02 0.03 -0.04 1.69 1.81 1zwbA3 LYS 12 HD3 0.18 0.01 -0.03 -0.04 1.68 1.80 1zwbA3 LYS 12 HE2 -0.14 -0.03 -0.11 -0.04 2.99 2.68 1zwbA3 LYS 12 HE3 -0.06 -0.02 -0.03 -0.04 2.99 2.83 1zwbA3 HIS 13 H 0.17 -0.00 0.00 -0.55 8.41 8.03 1zwbA3 HIS 13 HA 0.32 0.08 0.40 -0.75 4.63 4.67 1zwbA3 HIS 13 HB2 0.10 -0.06 0.16 -0.04 3.26 3.42 1zwbA3 HIS 13 HB3 0.15 0.18 -0.14 -0.04 3.20 3.35 1zwbA3 HIS 13 HD2 -0.03 -0.07 -0.05 -0.04 6.97 6.78 1zwbA3 HIS 13 HE1 0.01 -0.07 0.02 -0.04 7.75 7.66 1zwbA3 LEU 14 H -1.21 0.03 -0.00 -0.55 8.37 6.64 1zwbA3 LEU 14 HA -0.51 0.31 0.86 -0.75 4.35 4.25 1zwbA3 LEU 14 HB2 -0.43 -0.20 0.15 -0.04 1.64 1.13 1zwbA3 LEU 14 HB3 -0.41 0.16 0.00 -0.04 1.64 1.35 1zwbA3 LEU 14 HG -0.41 -0.02 -0.03 -0.04 1.64 1.13 1zwbA3 LEU 14 HD13 -0.88 -0.01 -0.09 -0.04 0.93 -0.09 1zwbA3 LEU 14 HD23 -1.29 -0.07 -0.21 -0.04 0.89 -0.72 1zwbA3 ASN 15 H -0.35 0.09 0.12 -0.55 8.53 7.84 1zwbA3 ASN 15 HA -0.17 0.21 0.53 -0.75 4.76 4.57 1zwbA3 ASN 15 HB2 -0.08 0.10 0.09 -0.04 2.88 2.95 1zwbA3 ASN 15 HB3 -0.15 0.01 0.16 -0.04 2.79 2.77 1zwbA3 ASN 15 HD21 -0.10 0.05 0.04 -0.04 7.03 6.98 1zwbA3 ASN 15 HD22 -0.05 -0.01 -0.01 -0.04 7.74 7.62 1zwbA3 SER 16 H -0.24 -0.02 -0.09 -0.55 8.46 7.57 1zwbA3 SER 16 HA 0.12 -0.04 0.33 -0.75 4.49 4.15 1zwbA3 SER 16 HB2 0.06 0.03 -0.24 -0.04 3.95 3.77 1zwbA3 SER 16 HB3 0.10 -0.03 0.15 -0.04 3.93 4.11 1zwbA3 MET 17 H 0.01 0.25 0.06 -0.55 8.47 8.25 1zwbA3 MET 17 HA 0.02 0.08 0.22 -0.75 4.52 4.09 1zwbA3 MET 17 HB2 -0.00 0.00 0.12 -0.04 2.15 2.23 1zwbA3 MET 17 HB3 -0.02 0.03 -0.01 -0.04 2.03 1.99 1zwbA3 MET 17 HG2 -0.00 0.06 -0.01 -0.04 2.63 2.64 1zwbA3 MET 17 HG3 0.01 0.00 0.04 -0.04 2.56 2.57 1zwbA3 MET 17 HE3 0.00 0.00 0.00 -0.04 2.10 2.07 1zwbA3 GLU 18 H -0.09 -0.09 -0.39 -0.55 8.60 7.49 1zwbA3 GLU 18 HA -0.05 0.09 0.38 -0.75 4.29 3.95 1zwbA3 GLU 18 HB2 -0.19 -0.11 0.07 -0.04 2.09 1.82 1zwbA3 GLU 18 HB3 -0.10 0.10 0.07 -0.04 1.99 2.01 1zwbA3 GLU 18 HG2 -0.10 0.11 0.05 -0.04 2.34 2.35 1zwbA3 GLU 18 HG3 -0.09 -0.02 0.05 -0.04 2.34 2.25 1zwbA3 ARG 19 H -0.10 0.44 -0.07 -0.55 8.46 8.18 1zwbA3 ARG 19 HA 0.04 0.22 0.80 -0.75 4.34 4.64 1zwbA3 ARG 19 HB2 -0.19 -0.03 -0.04 -0.04 1.90 1.60 1zwbA3 ARG 19 HB3 0.11 -0.15 0.08 -0.04 1.80 1.79 1zwbA3 ARG 19 HG2 0.06 0.08 0.07 -0.04 1.67 1.83 1zwbA3 ARG 19 HG3 0.21 0.20 0.03 -0.04 1.67 2.07 1zwbA3 ARG 19 HD2 0.30 -0.36 -0.14 -0.04 3.22 2.98 1zwbA3 ARG 19 HD3 0.11 0.04 0.12 -0.04 3.22 3.45 1zwbA3 VAL 20 H 0.14 0.25 0.05 -0.55 8.24 8.13 1zwbA3 VAL 20 HA 0.27 -0.04 0.26 -0.75 4.13 3.86 1zwbA3 VAL 20 HB 0.06 0.04 -0.65 -0.04 2.12 1.52 1zwbA3 VAL 20 HG13 0.06 0.09 -0.01 -0.04 0.97 1.07 1zwbA3 VAL 20 HG23 0.08 -0.01 -0.06 -0.04 0.95 0.92 1zwbA3 GLU 21 H 0.12 1.04 0.25 -0.55 8.60 9.46 1zwbA3 GLU 21 HA 0.06 0.06 0.35 -0.75 4.29 4.00 1zwbA3 GLU 21 HB2 0.07 0.17 0.13 -0.04 2.09 2.42 1zwbA3 GLU 21 HB3 0.05 -0.05 0.01 -0.04 1.99 1.96 1zwbA3 GLU 21 HG2 0.03 0.04 0.06 -0.04 2.34 2.43 1zwbA3 GLU 21 HG3 0.02 -0.03 0.07 -0.04 2.34 2.37 1zwbA3 TRP 22 H 0.31 0.00 -0.98 -0.55 7.97 6.76 1zwbA3 TRP 22 HA 0.01 0.19 0.20 -0.75 4.62 4.28 1zwbA3 TRP 22 HB2 0.02 0.14 -0.04 -0.04 3.23 3.31 1zwbA3 TRP 22 HB3 0.01 -0.29 -0.09 -0.04 3.23 2.83 1zwbA3 TRP 22 HD1 0.05 0.41 -0.18 -0.04 7.22 7.46 1zwbA3 TRP 22 HE1 0.07 0.09 -0.57 -0.04 10.20 9.76 1zwbA3 TRP 22 HE3 0.01 -0.26 -0.04 -0.04 7.59 7.26 1zwbA3 TRP 22 HZ2 0.05 0.05 -0.14 -0.04 7.44 7.36 1zwbA3 TRP 22 HZ3 0.01 0.11 0.00 -0.04 7.13 7.21 1zwbA3 TRP 22 HH2 0.02 0.02 -0.02 -0.04 7.19 7.16 1zwbA3 LEU 23 H 0.56 -0.00 -0.23 -0.55 8.37 8.14 1zwbA3 LEU 23 HA -0.77 0.07 0.34 -0.75 4.35 3.24 1zwbA3 LEU 23 HB2 0.08 0.05 0.10 -0.04 1.64 1.84 1zwbA3 LEU 23 HB3 0.61 -0.13 0.15 -0.04 1.64 2.22 1zwbA3 LEU 23 HG 0.10 0.26 0.00 -0.04 1.64 1.97 1zwbA3 LEU 23 HD13 0.01 -0.00 -0.23 -0.04 0.93 0.67 1zwbA3 LEU 23 HD23 0.15 -0.06 0.03 -0.04 0.89 0.98 1zwbA3 ARG 24 H 0.01 0.30 -0.58 -0.55 8.46 7.64 1zwbA3 ARG 24 HA -0.05 0.06 0.49 -0.75 4.34 4.10 1zwbA3 ARG 24 HB2 0.01 0.04 0.17 -0.04 1.90 2.07 1zwbA3 ARG 24 HB3 -0.02 -0.02 -0.00 -0.04 1.80 1.72 1zwbA3 ARG 24 HG2 -0.01 0.00 0.02 -0.04 1.67 1.64 1zwbA3 ARG 24 HG3 0.00 -0.01 -0.05 -0.04 1.67 1.57 1zwbA3 ARG 24 HD2 0.02 -0.02 -0.02 -0.04 3.22 3.15 1zwbA3 ARG 24 HD3 0.02 0.00 -0.04 -0.04 3.22 3.15 1zwbA3 LYS 25 H -0.08 0.58 -0.06 -0.55 8.42 8.31 1zwbA3 LYS 25 HA -0.08 0.01 0.45 -0.75 4.32 3.95 1zwbA3 LYS 25 HB2 -0.05 -0.05 -0.01 -0.04 1.87 1.72 1zwbA3 LYS 25 HB3 -0.09 0.08 -0.07 -0.04 1.79 1.67 1zwbA3 LYS 25 HG2 -0.09 0.14 -0.03 -0.04 1.46 1.44 1zwbA3 LYS 25 HG3 -0.09 -0.09 -0.05 -0.04 1.46 1.19 1zwbA3 LYS 25 HD2 -0.14 -0.25 -0.59 -0.04 1.69 0.67 1zwbA3 LYS 25 HD3 -0.08 0.04 -0.20 -0.04 1.68 1.40 1zwbA3 LYS 25 HE2 -0.35 0.15 -0.05 -0.04 2.99 2.69 1zwbA3 LYS 25 HE3 -0.20 -0.02 -0.06 -0.04 2.99 2.67 1zwbA3 LYS 26 H -0.28 0.22 -0.64 -0.55 8.42 7.17 1zwbA3 LYS 26 HA -0.29 0.05 0.29 -0.75 4.32 3.60 1zwbA3 LYS 26 HB2 -0.61 0.05 0.11 -0.04 1.87 1.38 1zwbA3 LYS 26 HB3 -0.29 -0.01 -0.01 -0.04 1.79 1.44 1zwbA3 LYS 26 HG2 -0.48 -0.01 -0.04 -0.04 1.46 0.89 1zwbA3 LYS 26 HG3 -0.32 -0.02 -0.00 -0.04 1.46 1.07 1zwbA3 LYS 26 HD2 -1.59 0.11 -0.25 -0.04 1.69 -0.08 1zwbA3 LYS 26 HD3 -1.96 -0.03 -0.15 -0.04 1.68 -0.51 1zwbA3 LYS 26 HE2 -0.15 -0.00 -0.18 -0.04 2.99 2.62 1zwbA3 LYS 26 HE3 -0.19 -0.00 -0.06 -0.04 2.99 2.70 1zwbA3 LEU 27 H -0.13 0.26 -0.24 -0.55 8.37 7.70 1zwbA3 LEU 27 HA -0.06 0.07 0.43 -0.75 4.35 4.04 1zwbA3 LEU 27 HB2 -0.06 -0.01 0.03 -0.04 1.64 1.56 1zwbA3 LEU 27 HB3 -0.07 0.02 0.08 -0.04 1.64 1.62 1zwbA3 LEU 27 HG -0.07 -0.02 0.07 -0.04 1.64 1.57 1zwbA3 LEU 27 HD13 -0.05 -0.01 -0.13 -0.04 0.93 0.71 1zwbA3 LEU 27 HD23 -0.06 0.01 0.07 -0.04 0.89 0.87 1zwbA3 GLN 28 H -0.06 0.16 -0.50 -0.55 8.47 7.53 1zwbA3 GLN 28 HA 0.03 0.02 0.64 -0.75 4.36 4.30 1zwbA3 GLN 28 HB2 -0.03 0.04 0.05 -0.04 2.15 2.16 1zwbA3 GLN 28 HB3 -0.05 0.04 0.14 -0.04 2.02 2.11 1zwbA3 GLN 28 HG2 -0.05 0.10 -0.12 -0.04 2.40 2.29 1zwbA3 GLN 28 HG3 0.00 -0.28 0.07 -0.04 2.39 2.15 1zwbA3 GLN 28 HE21 -0.03 0.44 0.13 -0.04 6.97 7.47 1zwbA3 GLN 28 HE22 -0.01 -0.03 0.03 -0.04 7.69 7.64 1zwbA3 ASP 29 H 0.05 0.28 -0.58 -0.55 8.40 7.60 1zwbA3 ASP 29 HA 0.41 0.08 0.80 -0.75 4.63 5.16 1zwbA3 ASP 29 HB2 -0.01 0.23 -0.01 -0.04 2.71 2.88 1zwbA3 ASP 29 HB3 0.05 -0.02 -0.01 -0.04 2.70 2.67 1zwbA3 VAL 30 H 0.04 0.33 0.11 -0.55 8.24 8.17 1zwbA3 VAL 30 HA -0.00 0.18 0.65 -0.75 4.13 4.21 1zwbA3 VAL 30 HB 0.03 0.02 0.17 -0.04 2.12 2.30 1zwbA3 VAL 30 HG13 0.01 0.00 0.12 -0.04 0.97 1.05 1zwbA3 VAL 30 HG23 -0.01 0.04 0.01 -0.04 0.95 0.95 1zwbA3 HIS 31 H 0.11 -0.00 -0.69 -0.55 8.41 7.28 1zwbA3 HIS 31 HA 0.01 0.12 0.49 -0.75 4.63 4.49 1zwbA3 HIS 31 HB2 -0.00 0.08 -0.25 -0.04 3.26 3.05 1zwbA3 HIS 31 HB3 0.00 -0.05 0.03 -0.04 3.20 3.14 1zwbA3 HIS 31 HD2 0.00 -0.02 -0.18 -0.04 6.97 6.74 1zwbA3 HIS 31 HE1 -0.00 -0.02 0.02 -0.04 7.75 7.70 1zwbA3 ASN 32 H 0.16 -0.05 0.01 -0.55 8.53 8.10 1zwbA3 ASN 32 HA 0.09 0.24 0.80 -0.75 4.76 5.13 1zwbA3 ASN 32 HB2 0.06 -0.14 0.09 -0.04 2.88 2.86 1zwbA3 ASN 32 HB3 0.05 0.06 -0.03 -0.04 2.79 2.83 1zwbA3 ASN 32 HD21 0.09 0.00 -0.01 -0.04 7.03 7.07 1zwbA3 ASN 32 HD22 0.07 0.04 -0.09 -0.04 7.74 7.72 1zwbA3 PHE 33 H 0.14 -0.16 -0.43 -0.55 8.34 7.33 1zwbA3 PHE 33 HA -0.02 0.26 0.35 -0.75 4.62 4.46 1zwbA3 PHE 33 HB2 -0.01 0.12 -0.10 -0.04 3.15 3.12 1zwbA3 PHE 33 HB3 -0.01 0.12 0.10 -0.04 3.06 3.23 1zwbA3 PHE 33 HD2 -0.02 -0.02 0.16 -0.04 7.28 7.36 1zwbA3 PHE 33 HE2 -0.02 -0.03 0.02 -0.04 7.38 7.31 1zwbA3 PHE 33 HZ -0.02 -0.04 -0.00 -0.04 7.32 7.22 1zwbA3 VAL 34 H -0.07 0.09 -0.17 -0.55 8.24 7.54 1zwbA3 VAL 34 HA -0.16 0.14 0.71 -0.75 4.13 4.06 1zwbA3 VAL 34 HB -0.04 -0.04 0.06 -0.04 2.12 2.06 1zwbA3 VAL 34 HG13 0.00 0.06 -0.10 -0.04 0.97 0.89 1zwbA3 VAL 34 HG23 0.00 -0.01 -0.12 -0.04 0.95 0.78 1zwbA3 ALA 35 H -0.22 0.38 0.11 -0.55 8.40 8.12 1zwbA3 ALA 35 HA -0.07 0.05 0.35 -0.75 4.34 3.91 1zwbA3 ALA 35 HB3 -0.07 -0.00 -0.00 -0.04 1.41 1.29 1zwbA3 LEU 36 H -0.05 0.12 0.04 -0.55 8.37 7.93 1zwbA3 LEU 36 HA -0.05 0.18 0.39 -0.75 4.35 4.11 1zwbA3 LEU 36 HB2 -0.02 -0.01 0.10 -0.04 1.64 1.67 1zwbA3 LEU 36 HB3 -0.01 0.01 0.07 -0.04 1.64 1.67 1zwbA3 LEU 36 HG -0.03 0.05 -0.01 -0.04 1.64 1.62 1zwbA3 LEU 36 HD13 -0.03 -0.01 -0.04 -0.04 0.93 0.81 1zwbA3 LEU 36 HD23 -0.01 0.00 0.02 -0.04 0.89 0.86