============================================================================= SHIFTS, version 4.1 [X.-P. Xu and D.A. Case, Mar. 2002] ============================================================================= shifts will be computed for atoms matching ::H* found 6 rings ring int. center anis. iso. HIS 8 0.900 9.891 4.710 -0.664 -99.200 -91.000 HIS 13 0.900 8.260 -9.500 0.987 -99.200 -91.000 TRP 22 1.040 1.754 -1.130 -0.583 -99.200 -91.000 TRP6 22 1.020 1.665 -0.162 -2.772 -99.200 -91.000 HIS 31 0.900 -11.942 5.853 -2.691 -99.200 -91.000 PHE 33 1.000 -8.331 15.277 -3.645 -99.200 -91.000 ============================================================================= Atom RingCur El P_anis Const RC pred Obs ============================================================================= 1zwbA5 VAL 1 HA -0.00 -0.14 0.19 -0.75 4.13 3.43 1zwbA5 VAL 1 HB 0.00 0.02 0.02 -0.04 2.12 2.11 1zwbA5 VAL 1 HG13 -0.00 -0.02 -0.07 -0.04 0.97 0.84 1zwbA5 VAL 1 HG23 0.00 -0.00 0.03 -0.04 0.95 0.94 1zwbA5 SER 2 H -0.01 0.01 0.01 -0.55 8.46 7.91 1zwbA5 SER 2 HA -0.02 -0.11 0.35 -0.75 4.49 3.96 1zwbA5 SER 2 HB2 -0.02 0.29 0.21 -0.04 3.95 4.38 1zwbA5 SER 2 HB3 -0.02 -0.07 0.05 -0.04 3.93 3.85 1zwbA5 GLU 3 H -0.05 0.08 0.08 -0.55 8.60 8.17 1zwbA5 GLU 3 HA -0.33 -0.04 0.29 -0.75 4.29 3.45 1zwbA5 GLU 3 HB2 -0.20 0.29 -0.16 -0.04 2.09 1.97 1zwbA5 GLU 3 HB3 -0.66 0.01 0.19 -0.04 1.99 1.49 1zwbA5 GLU 3 HG2 -0.06 0.04 -0.01 -0.04 2.34 2.26 1zwbA5 GLU 3 HG3 -0.03 -0.05 0.04 -0.04 2.34 2.26 1zwbA5 ILE 4 H -0.05 0.03 -0.44 -0.55 8.25 7.24 1zwbA5 ILE 4 HA 0.07 -0.20 0.26 -0.75 4.18 3.56 1zwbA5 ILE 4 HB -0.01 -0.15 0.03 -0.04 1.89 1.71 1zwbA5 ILE 4 HG12 -0.02 0.46 -0.48 -0.04 1.49 1.41 1zwbA5 ILE 4 HG13 -0.02 -0.24 -0.23 -0.04 1.21 0.68 1zwbA5 ILE 4 HG23 0.04 0.11 -0.26 -0.04 0.93 0.78 1zwbA5 ILE 4 HD13 -0.01 -0.02 -0.01 -0.04 0.88 0.80 1zwbA5 GLN 5 H 0.13 0.09 0.01 -0.55 8.47 8.14 1zwbA5 GLN 5 HA 0.01 0.30 0.81 -0.75 4.36 4.73 1zwbA5 GLN 5 HB2 0.02 0.12 0.15 -0.04 2.15 2.39 1zwbA5 GLN 5 HB3 0.05 0.02 0.04 -0.04 2.02 2.09 1zwbA5 GLN 5 HG2 0.07 -0.30 0.06 -0.04 2.40 2.18 1zwbA5 GLN 5 HG3 0.03 0.13 0.05 -0.04 2.39 2.56 1zwbA5 GLN 5 HE21 0.03 0.06 0.00 -0.04 6.97 7.02 1zwbA5 GLN 5 HE22 0.10 0.05 -0.00 -0.04 7.69 7.79 1zwbA5 LEU 6 H -0.01 0.33 -0.42 -0.55 8.37 7.72 1zwbA5 LEU 6 HA -0.06 0.04 0.26 -0.75 4.35 3.83 1zwbA5 LEU 6 HB2 -0.03 -0.01 -0.12 -0.04 1.64 1.44 1zwbA5 LEU 6 HB3 -0.03 0.15 0.12 -0.04 1.64 1.84 1zwbA5 LEU 6 HG -0.08 -0.02 0.10 -0.04 1.64 1.60 1zwbA5 LEU 6 HD13 -0.05 0.00 0.02 -0.04 0.93 0.86 1zwbA5 LEU 6 HD23 -0.05 0.01 0.05 -0.04 0.89 0.86 1zwbA5 MET 7 H -0.01 -0.24 -0.38 -0.55 8.47 7.29 1zwbA5 MET 7 HA -0.06 0.13 0.43 -0.75 4.52 4.26 1zwbA5 MET 7 HB2 -0.00 0.20 -0.43 -0.04 2.15 1.88 1zwbA5 MET 7 HB3 0.00 0.00 -0.07 -0.04 2.03 1.92 1zwbA5 MET 7 HG2 -0.04 -0.04 0.05 -0.04 2.63 2.56 1zwbA5 MET 7 HG3 -0.05 0.21 0.22 -0.04 2.56 2.90 1zwbA5 MET 7 HE3 -0.02 -0.01 -0.02 -0.04 2.10 2.00 1zwbA5 HIS 8 H 0.12 0.02 -0.02 -0.55 8.41 7.98 1zwbA5 HIS 8 HA 0.05 0.19 0.35 -0.75 4.63 4.47 1zwbA5 HIS 8 HB2 0.02 -0.01 0.03 -0.04 3.26 3.26 1zwbA5 HIS 8 HB3 0.03 -0.23 -0.37 -0.04 3.20 2.59 1zwbA5 HIS 8 HD2 0.10 0.03 0.14 -0.04 6.97 7.20 1zwbA5 HIS 8 HE1 0.02 0.00 0.02 -0.04 7.75 7.76 1zwbA5 ASN 9 H 0.04 -0.36 -0.41 -0.55 8.53 7.25 1zwbA5 ASN 9 HA 0.08 0.26 0.51 -0.75 4.76 4.86 1zwbA5 ASN 9 HB2 -0.06 -0.17 0.02 -0.04 2.88 2.63 1zwbA5 ASN 9 HB3 -0.19 -0.02 -0.11 -0.04 2.79 2.42 1zwbA5 ASN 9 HD21 -0.05 -0.04 -0.02 -0.04 7.03 6.87 1zwbA5 ASN 9 HD22 -0.05 0.07 -0.02 -0.04 7.74 7.71 1zwbA5 LEU 10 H -0.09 -0.03 -0.30 -0.55 8.37 7.40 1zwbA5 LEU 10 HA -0.47 0.05 0.52 -0.75 4.35 3.69 1zwbA5 LEU 10 HB2 -0.10 0.11 0.08 -0.04 1.64 1.68 1zwbA5 LEU 10 HB3 -0.04 -0.18 -0.06 -0.04 1.64 1.32 1zwbA5 LEU 10 HG -0.19 0.01 -0.02 -0.04 1.64 1.39 1zwbA5 LEU 10 HD13 -0.19 -0.00 -0.19 -0.04 0.93 0.51 1zwbA5 LEU 10 HD23 -0.17 0.03 -0.02 -0.04 0.89 0.69 1zwbA5 GLY 11 H -0.25 0.09 0.01 -0.55 8.43 7.73 1zwbA5 GLY 11 HA2 0.35 0.16 0.45 -0.51 4.01 4.46 1zwbA5 GLY 11 HA3 0.50 0.01 0.25 -0.51 4.01 4.27 1zwbA5 LYS 12 H 0.12 0.35 0.14 -0.55 8.42 8.47 1zwbA5 LYS 12 HA 0.07 0.02 0.26 -0.75 4.32 3.91 1zwbA5 LYS 12 HB2 0.05 -0.00 0.13 -0.04 1.87 2.01 1zwbA5 LYS 12 HB3 0.07 -0.03 -0.03 -0.04 1.79 1.75 1zwbA5 LYS 12 HG2 0.08 -0.10 -0.38 -0.04 1.46 1.03 1zwbA5 LYS 12 HG3 0.07 0.29 -0.01 -0.04 1.46 1.77 1zwbA5 LYS 12 HD2 0.04 -0.02 0.01 -0.04 1.69 1.68 1zwbA5 LYS 12 HD3 0.04 -0.05 -0.04 -0.04 1.68 1.59 1zwbA5 LYS 12 HE2 0.03 0.09 0.13 -0.04 2.99 3.20 1zwbA5 LYS 12 HE3 0.02 -0.04 0.03 -0.04 2.99 2.96 1zwbA5 HIS 13 H 0.08 0.04 -0.79 -0.55 8.41 7.20 1zwbA5 HIS 13 HA -0.05 -0.15 0.23 -0.75 4.63 3.91 1zwbA5 HIS 13 HB2 -0.01 -0.06 -0.15 -0.04 3.26 3.00 1zwbA5 HIS 13 HB3 -0.01 0.16 0.24 -0.04 3.20 3.55 1zwbA5 HIS 13 HD2 -0.01 -0.02 -0.01 -0.04 6.97 6.88 1zwbA5 HIS 13 HE1 -0.04 -0.05 -0.03 -0.04 7.75 7.59 1zwbA5 LEU 14 H 0.16 -0.02 -0.01 -0.55 8.37 7.95 1zwbA5 LEU 14 HA 0.02 0.14 0.40 -0.75 4.35 4.16 1zwbA5 LEU 14 HB2 -0.04 0.10 0.02 -0.04 1.64 1.68 1zwbA5 LEU 14 HB3 -0.00 -0.32 0.10 -0.04 1.64 1.38 1zwbA5 LEU 14 HG -0.10 -0.18 -0.01 -0.04 1.64 1.30 1zwbA5 LEU 14 HD13 -0.36 0.07 0.07 -0.04 0.93 0.66 1zwbA5 LEU 14 HD23 0.17 0.00 -0.35 -0.04 0.89 0.67 1zwbA5 ASN 15 H -0.02 -0.28 0.04 -0.55 8.53 7.73 1zwbA5 ASN 15 HA -0.08 0.21 0.52 -0.75 4.76 4.66 1zwbA5 ASN 15 HB2 -0.06 0.01 0.10 -0.04 2.88 2.89 1zwbA5 ASN 15 HB3 -0.15 0.23 0.08 -0.04 2.79 2.90 1zwbA5 ASN 15 HD21 -0.15 0.32 -0.32 -0.04 7.03 6.85 1zwbA5 ASN 15 HD22 -0.05 0.05 -0.04 -0.04 7.74 7.67 1zwbA5 SER 16 H -0.02 -0.01 0.19 -0.55 8.46 8.08 1zwbA5 SER 16 HA -0.00 0.32 0.94 -0.75 4.49 4.99 1zwbA5 SER 16 HB2 -0.01 0.09 -0.04 -0.04 3.95 3.95 1zwbA5 SER 16 HB3 -0.01 -0.09 0.19 -0.04 3.93 3.98 1zwbA5 MET 17 H 0.00 0.17 0.23 -0.55 8.47 8.32 1zwbA5 MET 17 HA 0.02 0.22 0.73 -0.75 4.52 4.74 1zwbA5 MET 17 HB2 0.01 0.02 0.13 -0.04 2.15 2.27 1zwbA5 MET 17 HB3 0.01 0.07 0.15 -0.04 2.03 2.22 1zwbA5 MET 17 HG2 0.01 -0.07 0.00 -0.04 2.63 2.52 1zwbA5 MET 17 HG3 0.01 0.08 0.04 -0.04 2.56 2.64 1zwbA5 MET 17 HE3 0.01 0.01 -0.19 -0.04 2.10 1.88 1zwbA5 GLU 18 H 0.01 -0.12 -0.02 -0.55 8.60 7.92 1zwbA5 GLU 18 HA 0.06 0.25 0.66 -0.75 4.29 4.50 1zwbA5 GLU 18 HB2 0.01 -0.19 0.17 -0.04 2.09 2.04 1zwbA5 GLU 18 HB3 0.05 0.16 -0.00 -0.04 1.99 2.16 1zwbA5 GLU 18 HG2 0.03 0.23 0.01 -0.04 2.34 2.57 1zwbA5 GLU 18 HG3 0.04 0.03 0.04 -0.04 2.34 2.40 1zwbA5 ARG 19 H 0.03 -0.16 -0.14 -0.55 8.46 7.64 1zwbA5 ARG 19 HA 0.05 0.08 0.34 -0.75 4.34 4.07 1zwbA5 ARG 19 HB2 -0.02 0.10 0.02 -0.04 1.90 1.96 1zwbA5 ARG 19 HB3 -0.01 -0.18 -0.07 -0.04 1.80 1.50 1zwbA5 ARG 19 HG2 0.00 0.22 -0.15 -0.04 1.67 1.71 1zwbA5 ARG 19 HG3 0.03 0.09 -0.17 -0.04 1.67 1.58 1zwbA5 ARG 19 HD2 0.04 -0.01 -0.40 -0.04 3.22 2.80 1zwbA5 ARG 19 HD3 0.01 -0.02 -0.10 -0.04 3.22 3.06 1zwbA5 VAL 20 H 0.07 -0.01 -0.86 -0.55 8.24 6.89 1zwbA5 VAL 20 HA 0.10 0.18 0.73 -0.75 4.13 4.40 1zwbA5 VAL 20 HB 0.04 0.03 0.01 -0.04 2.12 2.17 1zwbA5 VAL 20 HG13 0.04 -0.00 0.00 -0.04 0.97 0.96 1zwbA5 VAL 20 HG23 0.04 -0.06 0.06 -0.04 0.95 0.94 1zwbA5 GLU 21 H 0.08 0.29 -0.17 -0.55 8.60 8.26 1zwbA5 GLU 21 HA 0.04 0.02 0.39 -0.75 4.29 3.98 1zwbA5 GLU 21 HB2 0.04 0.03 0.21 -0.04 2.09 2.33 1zwbA5 GLU 21 HB3 0.08 0.06 0.33 -0.04 1.99 2.43 1zwbA5 GLU 21 HG2 0.04 -0.00 0.02 -0.04 2.34 2.36 1zwbA5 GLU 21 HG3 0.06 0.02 -0.22 -0.04 2.34 2.16 1zwbA5 TRP 22 H 0.27 0.50 -0.36 -0.55 7.97 7.83 1zwbA5 TRP 22 HA 0.01 0.04 0.37 -0.75 4.62 4.28 1zwbA5 TRP 22 HB2 0.02 0.01 0.07 -0.04 3.23 3.28 1zwbA5 TRP 22 HB3 0.02 0.10 0.10 -0.04 3.23 3.40 1zwbA5 TRP 22 HD1 0.03 -0.08 0.03 -0.04 7.22 7.15 1zwbA5 TRP 22 HE1 0.04 0.04 -0.22 -0.04 10.20 10.02 1zwbA5 TRP 22 HE3 0.01 0.01 -0.29 -0.04 7.59 7.28 1zwbA5 TRP 22 HZ2 0.01 0.06 0.05 -0.04 7.44 7.52 1zwbA5 TRP 22 HZ3 0.00 -0.01 -0.03 -0.04 7.13 7.05 1zwbA5 TRP 22 HH2 -0.01 0.02 0.01 -0.04 7.19 7.17 1zwbA5 LEU 23 H 0.40 0.31 -0.14 -0.55 8.37 8.39 1zwbA5 LEU 23 HA 0.33 0.01 0.39 -0.75 4.35 4.33 1zwbA5 LEU 23 HB2 0.23 -0.02 0.17 -0.04 1.64 1.98 1zwbA5 LEU 23 HB3 0.18 0.09 0.35 -0.04 1.64 2.22 1zwbA5 LEU 23 HG 0.09 -0.04 0.03 -0.04 1.64 1.67 1zwbA5 LEU 23 HD13 0.06 0.04 -0.23 -0.04 0.93 0.75 1zwbA5 LEU 23 HD23 0.10 -0.01 0.03 -0.04 0.89 0.96 1zwbA5 ARG 24 H 0.07 0.57 -0.42 -0.55 8.46 8.12 1zwbA5 ARG 24 HA -0.01 0.04 0.56 -0.75 4.34 4.18 1zwbA5 ARG 24 HB2 0.01 -0.03 0.00 -0.04 1.90 1.84 1zwbA5 ARG 24 HB3 0.01 0.07 0.16 -0.04 1.80 2.00 1zwbA5 ARG 24 HG2 -0.05 -0.05 -0.13 -0.04 1.67 1.40 1zwbA5 ARG 24 HG3 -0.03 -0.02 -0.00 -0.04 1.67 1.58 1zwbA5 ARG 24 HD2 -0.03 -0.01 -0.04 -0.04 3.22 3.09 1zwbA5 ARG 24 HD3 -0.01 -0.04 -0.01 -0.04 3.22 3.12 1zwbA5 LYS 25 H -0.06 0.79 0.14 -0.55 8.42 8.73 1zwbA5 LYS 25 HA -0.09 -0.01 0.44 -0.75 4.32 3.90 1zwbA5 LYS 25 HB2 -0.13 0.20 0.21 -0.04 1.87 2.11 1zwbA5 LYS 25 HB3 -0.25 0.02 0.00 -0.04 1.79 1.51 1zwbA5 LYS 25 HG2 -0.07 -0.03 0.05 -0.04 1.46 1.37 1zwbA5 LYS 25 HG3 -0.08 -0.02 0.01 -0.04 1.46 1.33 1zwbA5 LYS 25 HD2 -0.09 -0.00 -0.02 -0.04 1.69 1.53 1zwbA5 LYS 25 HD3 -0.15 0.01 -0.06 -0.04 1.68 1.45 1zwbA5 LYS 25 HE2 -0.06 -0.01 -0.01 -0.04 2.99 2.86 1zwbA5 LYS 25 HE3 -0.05 0.01 -0.03 -0.04 2.99 2.87 1zwbA5 LYS 26 H -0.24 0.51 -0.29 -0.55 8.42 7.85 1zwbA5 LYS 26 HA -0.28 0.04 0.43 -0.75 4.32 3.76 1zwbA5 LYS 26 HB2 -0.27 0.13 0.12 -0.04 1.87 1.81 1zwbA5 LYS 26 HB3 -0.13 -0.00 -0.02 -0.04 1.79 1.60 1zwbA5 LYS 26 HG2 -0.64 -0.01 -0.00 -0.04 1.46 0.77 1zwbA5 LYS 26 HG3 -0.44 -0.02 0.05 -0.04 1.46 1.01 1zwbA5 LYS 26 HD2 -0.97 0.04 0.02 -0.04 1.69 0.74 1zwbA5 LYS 26 HD3 -3.41 -0.05 -0.06 -0.04 1.68 -1.88 1zwbA5 LYS 26 HE2 -1.18 -0.01 -0.03 -0.04 2.99 1.73 1zwbA5 LYS 26 HE3 -0.65 0.02 -0.01 -0.04 2.99 2.31 1zwbA5 LEU 27 H -0.06 0.30 -0.26 -0.55 8.37 7.81 1zwbA5 LEU 27 HA 0.05 0.05 0.51 -0.75 4.35 4.20 1zwbA5 LEU 27 HB2 0.00 0.16 0.25 -0.04 1.64 2.01 1zwbA5 LEU 27 HB3 0.01 -0.00 0.03 -0.04 1.64 1.64 1zwbA5 LEU 27 HG 0.06 -0.02 0.05 -0.04 1.64 1.69 1zwbA5 LEU 27 HD13 0.16 -0.01 0.06 -0.04 0.93 1.09 1zwbA5 LEU 27 HD23 0.04 0.02 0.03 -0.04 0.89 0.94 1zwbA5 GLN 28 H -0.06 0.56 -0.09 -0.55 8.47 8.34 1zwbA5 GLN 28 HA -0.08 -0.00 0.41 -0.75 4.36 3.93 1zwbA5 GLN 28 HB2 -0.10 0.11 0.11 -0.04 2.15 2.23 1zwbA5 GLN 28 HB3 -0.07 0.07 0.05 -0.04 2.02 2.04 1zwbA5 GLN 28 HG2 -0.08 -0.03 0.10 -0.04 2.40 2.35 1zwbA5 GLN 28 HG3 -0.10 -0.02 0.01 -0.04 2.39 2.24 1zwbA5 GLN 28 HE21 0.01 -0.06 0.03 -0.04 6.97 6.91 1zwbA5 GLN 28 HE22 -0.01 -0.00 -0.04 -0.04 7.69 7.60 1zwbA5 ASP 29 H -0.04 0.33 -0.59 -0.55 8.40 7.54 1zwbA5 ASP 29 HA -0.04 -0.00 0.42 -0.75 4.63 4.25 1zwbA5 ASP 29 HB2 -0.11 0.24 0.23 -0.04 2.71 3.03 1zwbA5 ASP 29 HB3 -0.09 -0.05 0.00 -0.04 2.70 2.52 1zwbA5 VAL 30 H 0.02 0.34 -0.16 -0.55 8.24 7.89 1zwbA5 VAL 30 HA -0.10 0.02 0.51 -0.75 4.13 3.80 1zwbA5 VAL 30 HB 0.03 0.10 0.10 -0.04 2.12 2.31 1zwbA5 VAL 30 HG13 0.04 -0.01 -0.00 -0.04 0.97 0.95 1zwbA5 VAL 30 HG23 -0.04 0.02 0.06 -0.04 0.95 0.95 1zwbA5 HIS 31 H 0.21 0.21 -0.29 -0.55 8.41 8.00 1zwbA5 HIS 31 HA 0.06 0.00 0.33 -0.75 4.63 4.27 1zwbA5 HIS 31 HB2 0.01 0.08 0.19 -0.04 3.26 3.50 1zwbA5 HIS 31 HB3 0.02 -0.02 -0.02 -0.04 3.20 3.14 1zwbA5 HIS 31 HD2 0.01 -0.01 0.01 -0.04 6.97 6.93 1zwbA5 HIS 31 HE1 0.01 -0.04 -0.04 -0.04 7.75 7.64 1zwbA5 ASN 32 H 0.11 0.32 -0.31 -0.55 8.53 8.10 1zwbA5 ASN 32 HA 0.09 0.00 0.49 -0.75 4.76 4.58 1zwbA5 ASN 32 HB2 0.04 -0.06 0.08 -0.04 2.88 2.90 1zwbA5 ASN 32 HB3 0.03 0.06 0.13 -0.04 2.79 2.96 1zwbA5 ASN 32 HD21 0.04 -0.04 0.04 -0.04 7.03 7.03 1zwbA5 ASN 32 HD22 0.03 -0.06 -0.02 -0.04 7.74 7.65 1zwbA5 PHE 33 H 0.05 0.23 -0.08 -0.55 8.34 7.98 1zwbA5 PHE 33 HA -0.01 -0.07 0.41 -0.75 4.62 4.19 1zwbA5 PHE 33 HB2 -0.02 0.16 -0.38 -0.04 3.15 2.86 1zwbA5 PHE 33 HB3 -0.01 0.00 0.18 -0.04 3.06 3.19 1zwbA5 PHE 33 HD2 -0.03 0.06 0.04 -0.04 7.28 7.32 1zwbA5 PHE 33 HE2 -0.02 -0.05 -0.00 -0.04 7.38 7.26 1zwbA5 PHE 33 HZ -0.02 -0.05 0.00 -0.04 7.32 7.22 1zwbA5 VAL 34 H -0.24 0.13 0.09 -0.55 8.24 7.67 1zwbA5 VAL 34 HA 0.05 0.20 0.68 -0.75 4.13 4.30 1zwbA5 VAL 34 HB -0.05 -0.01 0.14 -0.04 2.12 2.16 1zwbA5 VAL 34 HG13 -0.00 -0.00 0.10 -0.04 0.97 1.02 1zwbA5 VAL 34 HG23 -0.08 0.01 -0.04 -0.04 0.95 0.80 1zwbA5 ALA 35 H 0.36 0.32 -0.51 -0.55 8.40 8.03 1zwbA5 ALA 35 HA 0.10 0.00 0.50 -0.75 4.34 4.18 1zwbA5 ALA 35 HB3 0.22 0.03 -0.05 -0.04 1.41 1.57 1zwbA5 LEU 36 H 0.04 0.09 0.02 -0.55 8.37 7.97 1zwbA5 LEU 36 HA -0.06 0.12 0.27 -0.75 4.35 3.93 1zwbA5 LEU 36 HB2 -0.03 -0.02 0.06 -0.04 1.64 1.61 1zwbA5 LEU 36 HB3 -0.04 0.22 0.03 -0.04 1.64 1.81 1zwbA5 LEU 36 HG 0.02 -0.10 -0.12 -0.04 1.64 1.41 1zwbA5 LEU 36 HD13 0.00 -0.00 -0.01 -0.04 0.93 0.88 1zwbA5 LEU 36 HD23 0.05 0.00 -0.22 -0.04 0.89 0.69