#******************************************************************* # # $Source: /sc/CvsTree/sc/gen/src/prg/scripts/tix/prosol/lib/lists/default,v $ # # Copyright (c) 1999 # BRUKER ANALYTIK GMBH # D-76287 Rheinstetten, Germany # # All Rights Reserved # # # $Id: default,v 1.15.2.3 2009/03/03 14:31:58 ber Exp $ # #******************************************************************* #../conf/instr/spect/prosol/relations/default #avance-version (09/03/03) # #pulses # P[0]=P90[F1]; # 90 deg pulse F1 P[1]=P90[F1]; # 90 deg pulse F1 P[2]=P90[F1]*2; # 180 deg pulse F1 P[3]=P90[F2]; # 90 deg pulse F2 P[4]=P90[F2]*2; # 180 deg pulse F2 P[5]=PTOC[F1]*0.66; # 60 deg pulse F1, TOCSY P[6]=PTOC[F1]; # 90 deg pulse F1, TOCSY P[7]=PTOC[F1]*2; # 180 deg pulse F1, TOCSY P[8]=PSH3[F1]; # 90 deg selective F1, WET P[9]=PTOC[F2]; # 90 deg pulse F2, TOCSY P[10]=PTOC[F2]*2; # 180 deg pulse F2, TOCSY P[11]=PSH1[F1]; # 90 deg selective F1 P[12]=PSH2[F1]; # 180 deg selective F1 # P[14]=PSH3[F2]; # 180 deg inversion, adiabatic P[15]=TROE[F1]; # cw pulse F1, ROESY P[18]=PSH7[F1]; # off-resonance presat F1 P[21]=P90[F3]; # 90 deg pulse F3 P[22]=P90[F3]*2; # 180 deg pulse F3 P[23]=P90[F4]; # 90 deg pulse F4 P[24]=PSH2[F2]; # 180 deg refocussing, adiabatic P[25]=PROE[F1]*2; # 180 deg pulse, Shaka ROESY P[26]=PSH12[F1]; # 180 deg inversion F1, adiabatic P[27]=P90[F1]; # 90 deg pulse F1, WATERGATE # P[29]=PSH8[F1]; # flip back pulse P[31]=PSH15[F2]; # 180 deg adiabatic, F2, 13C x-filter P[32]=PSH16[F1]; # 180 deg adiabatic, F1, z-spoil #P[33]=PSH[F1]; # 90 deg, F1, hadamard #P[34]=PSH[F1]; # 180 deg, F1, hadamard #P[35]=PSH[F2]; # 90 deg, F2, hadamard #P[36]=PSH[F2]; # 180 deg, F2, hadamard #P[37]=PSH[F3]; # 90 deg, F3, hadamard #P[38]=PSH[F3]; # 180 deg, F3, hadamard P[39]=PSH21[F2]; # 180 deg, F2, Bip P[40]=PSH8[F1]*2; # 180 deg sel. F1, 1H (exc. scul) # P[63]=PSH11[F2]; # 180 deg adiabatic decoupling, F2, 13C # #decoupling pulses # PCPD[1]=PCPDP[F1]; # 90 deg pulse F1, dec. PCPD[2]=PCPDP[F2]; # 90 deg pulse F2, dec. PCPD[3]=PCPDP[F3]; # 90 deg pulse F3, dec. # #power levels # PL[1]=PL90[F1]; # high power, F1 PL[2]=PL90[F2]; # high power, F2 PL[3]=PL90[F3]; # high power, F3 PL[4]=PL90[F4]; # high power, F4 PL[9]=PLCW[F1]; # presat power, F1 PL[10]=PLTOC[F1]; # TOCSY power, F1 PL[11]=PLROE[F1]; # ROESY power, F1 PL[12]=PLCPDP[F2]; # dec. power, F2 PL[13]=PLCPD2[F2]; # dec. power 2, F2 PL[14]=PLNOE[F2]; # low power cw, F2 PL[15]=PLTOC[F2]; # TOCSY power, F2 PL[16]=PLCPDP[F3]; # dec. power, F3 PL[18]=PL90[F1]; # WATERGATE power, F1 PL[19]=PLCPDP[F1]; # dec. power, F1 PL[21]=PLCW[F2]; # PL[23]=PLTOC[F3]; # TOCSY power, F3 PL[24]=PLHD[F2]; # HD decoupling, F2 PL[25]=PLSH8U[F2]; # Eretic, F2 PL[27]=PLROE[F1]; # Shaka Spinlock PL[30]=PLCPDP[F2]; # dec. power, F2, 13C (=pl12) PL[31]=PLUSER2[F2]; # dec. power, F2, 13C, cw bilev # #shapes # SP[1]=PLSH1[F1]; # 90 deg selective F1 SP[2]=PLSH2[F1]; # 180 deg selective F1 SP[3]=PLSH3[F2]; # adiabatic 180 deg, F2, inversion SP[4]=PLSH21[F2]; # 180 deg Bip, F2, inversion SP[5]=PLSH8[F1]; # flip-back pulse, F1, 1H SP[6]=PLSH7[F1]; # off-resonance presat F1 SP[7]=PLSH2[F2]; # adiabatic 180 deg, F2, refocussing SP[8]=PLSH12[F1]; # adiabatic 180 deg, F1, inversion SP[11]=PLSH8[F1]; # flip-back pulse, F1, H SP[14]=PLSH12[F2]; # adiab. bilev dec., F2, 13C SP[18]=PLSH15[F2]; # adiabatic 180 deg, F2, 13C, x-filter SP[19]=PLSH3[F1] +0.87; # 90 deg, F1, wet SP[20]=PLSH3[F1] -1.04; # 90 deg, F1, wet SP[21]=PLSH3[F1] +2.27; # 90 deg, F1, wet SP[22]=PLSH3[F1] -5.05; # 90 deg, F1, wet #SP[23]=PLSH[F1]; # 90 deg, F1, hadamard #SP[24]=PLSH[F1]; # 180 deg, F1, hadamard #SP[25]=PLSH[F2]; # 90 deg, F2, hadamard #SP[26]=PLSH[F2]; # 180 deg, F2, hadamard #SP[27]=PLSH[F3]; # 90 deg, F3, hadamard #SP[28]=PLSH[F3]; # 180 deg, F3, hadamard SP[29]=PLSH16[F1]; # adiabatic 180 deg, F1, z-spoil SP[31]=PLSH11[F2]; # adiab. dec., F2, 13C # SPNAM1=PNSH1[F1]; # SPNAM2=PNSH2[F1]; # SPNAM3=PNSH3[F2]; # SPNAM4=PNSH21[F2]; # SPNAM6=PNSH7[F1]; # SPNAM7=PNSH2[F2]; # SPNAM8=PNSH12[F1]; # SPNAM10=PNSH8[F1]; # SPNAM11=PNSH8[F1]; # SPNAM14=PNSH12[F2]; # SPNAM15=PNSH8U[F2]; # Eretic, F2 SPNAM18=PNSH15[F2]; # SPNAM19=PNSH3[F1]; # SPNAM20=PNSH3[F1]; # SPNAM21=PNSH3[F1]; # SPNAM22=PNSH3[F1]; # #SPNAM23=PNSH[]; # #SPNAM24=PNSH[]; # #SPNAM25=PNSH[]; # #SPNAM26=PNSH[]; # #SPNAM27=PNSH[]; # #SPNAM28=PNSH[]; # SPNAM29=PNSH16[F1]; # SPNAM31=PNSH11[F2]; # # SPOAL[1]=PASH1[F1]; # SPOAL[2]=PASH2[F1]; # SPOAL[3]=PASH3[F2]; # SPOAL[4]=PASH21[F2]; # SPOAL[6]=PASH7[F1]; # SPOAL[7]=PASH2[F2]; # SPOAL[8]=PASH12[F1]; # SPOAL[10]=PASH8[F1]; SPOAL[11]=PASH8[F1]; SPOAL[14]=PASH12[F2]; # SPOAL[18]=PASH15[F2]; # SPOAL[19]=PASH3[F1]; # SPOAL[20]=PASH3[F1]; # SPOAL[21]=PASH3[F1]; # SPOAL[22]=PASH3[F1]; # #SPOAL[23]=PASH[]; # #SPOAL[24]=PASH[]; # #SPOAL[25]=PASH[]; # #SPOAL[26]=PASH[]; # #SPOAL[27]=PASH[]; # #SPOAL[28]=PASH[]; # SPOAL[29]=PASH16[F1]; # SPOAL[31]=PASH11[F2]; # # #global # D[9]=TTOC[F1]; # D[16]=D_grad; # P[16]=P_grad1; # P[17]=P_mlev; # P[19]=P_grad2; # P[20]=P_mlev; # P[28]=P_hsqc; # #