# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d"
;hsqct2etf3gpsi3d
;avance-version (07/04/04)
;3D H-1/X correlation via double inept transfer
;   using sensitivity improvement
;for measuring N-15 T2 relaxation times
;phase sensitive using Echo/Antiecho-TPPI gradient selection
;with decoupling during acquisition
;using f3 - channel
;using flip-back pulse
;as pseudo3D
;(use parameterset HSQCT2ETF3GPSI3D)
;
;$CLASS=HighRes
;$DIM=3D
;$TYPE=
;$SUBTYPE=
;$COMMENT=


prosol relations=<triple>


# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/Avance.incl" 1
;Avance2.incl
;   for 1
;
;avance-version (07/08/21)
;
;$CLASS=HighRes Incl
;$COMMENT=





































































































































;$Id: Avance2.incl,v 1.17.2.1 2007/09/14 16:17:35 ber Exp $
# 23 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d" 2

# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/Grad.incl" 1
;Grad2.incl  -  include file for Gradient Spectroscopy
;   for 1
;
;avance-version (07/01/17)
;
;$CLASS=HighRes Incl
;$COMMENT=



















define list<gradient> EA=<EA>



;$Id: Grad2.incl,v 1.12 2007/01/22 14:22:35 ber Exp $
# 24 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d" 2

# 1 "/opt/topspin2.1/exp/stan/nmr/lists/pp/Delay.incl" 1
;Delay.incl  -  include file for commonly used delays
;
;version 00/02/07
;
;$CLASS=HighRes Incl
;$COMMENT=


;general delays

define delay DELTA
define delay DELTA1
define delay DELTA2
define delay DELTA3
define delay DELTA4
define delay DELTA5
define delay DELTA6
define delay DELTA7
define delay DELTA8

define delay TAU
define delay TAU1
define delay TAU2
define delay TAU3
define delay TAU4
define delay TAU5


;delays for centering pulses

define delay CEN_HN1
define delay CEN_HN2
define delay CEN_HN3
define delay CEN_HC1
define delay CEN_HC2
define delay CEN_HC3
define delay CEN_HC4
define delay CEN_HP1
define delay CEN_HP2
define delay CEN_CN1
define delay CEN_CN2
define delay CEN_CN3
define delay CEN_CN4
define delay CEN_CP1
define delay CEN_CP2


;loop counters

define loopcounter COUNTER
define loopcounter SCALEF
define loopcounter FACTOR1
define loopcounter FACTOR2
define loopcounter FACTOR3



;$Id: Delay.incl,v 1.12 2005/11/10 12:16:58 ber Exp $
# 25 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d" 2




"p2=p1*2"
"p22=p21*2"
"d11=30m"
"d12=20u"
"d24=1s/(cnst4*cnst11)"
"d25=1s/(cnst4*cnst12)"
"d26=1s/(cnst4*4)"

"d21=450u"

"d31=(p30*16+d21*32)"

		
"d10=3u"

"in10=inf2/2"

"DELTA2=p16+d16+8u"
"DELTA3=d21-p2/2"
"DELTA4=d25-p16-d16"




"DELTA1=d25-p16-d16-p2-d10*2-p21*4/3.1415"



"spoff1=0"
"spoff13=bf2*((cnst21+cnst22)/2000000)-o2"


aqseq 312


# 1 "mc_line 64 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d expanding definition part of mc command before ze"
; dimension 3 aq-mode (F2) QF (F1) Echo-Antiecho  F2->F1
define delay MCWRK
define delay MCREST
define loopcounter ST1CNT
"ST1CNT = td2 / (2)"
"MCWRK = d1"
"MCREST = d1 - d1"
    dccorr
# 64 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d"
1 ze
# 1 "mc_line 64 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d expanding definition of mc command after ze"
# 65 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d"
  d11 pl16:f3 st0
2 6m do:f3 
3 3m
# 1 "mc_line 68 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d expanding start label for mc command"
4 MCWRK
  MCREST
# 69 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d"

  (p1 ph1)
  d26 pl3:f3
  (center (p2 ph1) (p22 ph1):f3 )
  d26 setnmr3|0 setnmr0|34|32|33 ctrlgrad 0
  (p1 ph2)

  4u pl0:f1
  (p11:sp1 ph1:r):f1
  4u
  p16:gp1
  d16 pl1:f1

  (p21 ph3):f3
  d25 
  (center (p2 ph1) (p22 ph6):f3 )
  d25 pl23:f3

6 d21
  (p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6):f3
  DELTA3
  (p2 ph1)
  DELTA3
  (p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6):f3
  d21*2
  (p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6):f3
  DELTA3
  (p2 ph8)
  DELTA3
  (p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6 d21*2 p30 ph6):f3
  d21
  lo to 6 times c

  p16:gp2*-1*EA
  d16
  DELTA4 pl3:f3
  (p22 ph6):f3
  d10 




  (p2 ph7)


  d10
  p16:gp2*EA
  d16
  DELTA1

  (center (p1 ph1) (p21 ph4):f3 )
  d24
  (center (p2 ph1) (p22 ph1):f3 )
  d24
  (center (p1 ph2) (p21 ph5):f3 )
  d26
  (center (p2 ph1) (p22 ph1):f3 )
  d26
  (p1 ph1)
  DELTA2
  (p2 ph1)
  4u
  p16:gp3
  d16 pl16:f3
  4u  setnmr3^0 setnmr0^34^32^33 ctrlgrad 7
  goscnp ph31 cpd3:f3

  3m do:f3
  3m st ivc
  lo to 3 times nbl

  3m ipp3 ipp4 ipp5 ipp6 ipp7 ipp31
  lo to 4 times ns

# 1 "mc_line 143 file /opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d expanding mc command in line"
  MCWRK  wr #0 if #0 zd
  MCWRK
# 146 "/opt/topspin2.1/exp/stan/nmr/lists/pp/hsqct2etf3gpsi3d"
  d31
exit
   

ph0=0 
ph1=0 
ph2=1
ph3=0 2 
ph4=0 0 2 2
ph5=3 3 1 1
ph6=0 0 0 0 2 2 2 2
ph7=0 0 2 2
ph8=2
ph31=0 2 2 0
  

;pl0 : 120dB
;pl1 : f1 channel - power level for pulse (default)
;pl3 : f3 channel - power level for pulse (default)
;pl16: f3 channel - power level for CPD/BB decoupling
;pl23: f3 channel - power level for TOCSY-spinlock
;sp1 : f1 channel - shaped pulse  90 degree
;sp13: f2 channel - shaped pulse 180 degree  (Ca and C=O, adiabatic)
;p1 : f1 channel -  90 degree high power pulse
;p2 : f1 channel - 180 degree high power pulse
;p8 : f2 channel - 180 degree shaped pulse for inversion (adiabatic)
;p11: f1 channel -  90 degree shaped pulse
;p16: homospoil/gradient pulse
;p21: f3 channel -  90 degree high power pulse
;p22: f3 channel - 180 degree high power pulse
;p30: f3 channel - 180 degree pulse at pl23
;d1 : relaxation delay; 1-5 * T1
;d10 : incremented delay                             [3 usec]
;d11: delay for disk I/O                             [30 msec]
;d12: delay for power switching                      [20 usec]
;d16: delay for homospoil/gradient recovery
;d21: echo delay                                     [450 usec]
;d24: 1/(4J)YH for YH
;     1/(8J)YH for all multiplicities
;d25: 1/(4J)YH for YH
;     1/(8J)YH for all multiplicities
;d26: 1/(4J(YH))
;d31: length of single cpmg loop
;cnst4: = J(YH)
;cnst11: for multiplicity selection = 4 for NH, 8 for all multiplicities
;cnst12: for multiplicity selection = 4 for NH, 8 for all multiplicities
;cnst21: CO chemical shift (offset, in ppm)
;cnst22: Calpha chemical shift (offset, in ppm)
;vc : variable loop-coounter for T2 delay, taken from vc-list
;inf2: 1/SW(X) = 2 * DW(X)
;in10: 1/(2 * SW(X)) = DW(X)
;nd10: 2
;NS: 2 * n
;DS: >= 16
;td1: number of delays in vc-list
;td2: number of experiments in F2
;NBL: = td1
;FnMODE: QF in F1
;FnMODE: echo-antiecho in F2
;cpd3: decoupling according to sequence defined by cpdprg3
;pcpd3: f3 channel - 90 degree pulse for decoupling sequence


;use gradient ratio:	gp 1 : gp 2 : gp 3
;			  30 :   80 : 16.2   for N-15

;for z-only gradients:
;gpz1: 30%
;gpz2: 80%
;gpz3: 16.2%

;use gradient files:   
;gpnam1: SINE.100
;gpnam2: SINE.100
;gpnam3: SINE.100


                                          ;preprocessor-flags-start
;LABEL_CN: for C-13 and N-15 labeled samples start experiment with 
;             option -DLABEL_CN (eda: ZGOPTNS)
                                          ;preprocessor-flags-end



;$Id: hsqct2etf3gpsi3d,v 1.5 2007/04/11 13:34:30 ber Exp $