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      <PDBx:audit_author pdbx_ordinal="1">
         <PDBx:name>Spyroulias, G.A.</PDBx:name>
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      <PDBx:audit_author pdbx_ordinal="2">
         <PDBx:name>Galanis, A.S.</PDBx:name>
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      <PDBx:audit_author pdbx_ordinal="3">
         <PDBx:name>Petrou, C.</PDBx:name>
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      <PDBx:audit_author pdbx_ordinal="4">
         <PDBx:name>Vahliotis, D.</PDBx:name>
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      <PDBx:audit_author pdbx_ordinal="5">
         <PDBx:name>Sotiriou, P.</PDBx:name>
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         <PDBx:name>Nikolopoulou, A.</PDBx:name>
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         <PDBx:name>Nock, B.</PDBx:name>
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         <PDBx:name>Maina, T.</PDBx:name>
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         <PDBx:name>Cordopatis, P.</PDBx:name>
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         <PDBx:name>D-PHENYLALANINE</PDBx:name>
         <PDBx:type>D-peptide linking</PDBx:type>
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      <PDBx:chem_comp id="CYS">
         <PDBx:formula>C3 H7 N O2 S</PDBx:formula>
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         <PDBx:name>CYSTEINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="TYR">
         <PDBx:formula>C9 H11 N O3</PDBx:formula>
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         <PDBx:name>TYROSINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
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         <PDBx:formula>C11 H12 N2 O2</PDBx:formula>
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         <PDBx:name>D-TRYPTOPHAN</PDBx:name>
         <PDBx:type>D-peptide linking</PDBx:type>
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         <PDBx:formula>C6 H15 N2 O2 1</PDBx:formula>
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         <PDBx:name>LYSINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
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         <PDBx:formula>C4 H9 N O3</PDBx:formula>
         <PDBx:formula_weight>119.120</PDBx:formula_weight>
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         <PDBx:name>THREONINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
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         <PDBx:name>3-[(2-AMINOETHYL)AMINO]-2-{[(2-AMINOETHYL)AMINO]METHYL}PROPANAL</PDBx:name>
         <PDBx:type>non-polymer</PDBx:type>
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      <PDBx:citation id="primary">
         <PDBx:country>US</PDBx:country>
         <PDBx:journal_abbrev>Med.Chem.</PDBx:journal_abbrev>
         <PDBx:journal_id_CSD>0353</PDBx:journal_id_CSD>
         <PDBx:journal_id_ISSN>1573-4064</PDBx:journal_id_ISSN>
         <PDBx:journal_volume>1</PDBx:journal_volume>
         <PDBx:page_first>487</PDBx:page_first>
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         <PDBx:pdbx_database_id_PubMed>16787334</PDBx:pdbx_database_id_PubMed>
         <PDBx:title>3D solution structure of [Tyr3]octreotate derivatives in DMSO: structure differentiation of peptide core due to chelate group attachment and biologically active conformation.</PDBx:title>
         <PDBx:year>2005</PDBx:year>
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      <PDBx:citation_author citation_id="primary" name="Spyroulias, G.A." ordinal="1"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Galanis, A.S." ordinal="2"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Petrou, C.h." ordinal="3"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Vahliotis, D." ordinal="4"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Sotiriou, P." ordinal="5"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Nikolopoulou, A." ordinal="6"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Nock, B." ordinal="7"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Maina, T." ordinal="8"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Cordopatis, P." ordinal="9"></PDBx:citation_author>
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      <PDBx:database_PDB_rev num="1">
         <PDBx:date>2005-09-20</PDBx:date>
         <PDBx:date_original>2005-01-19</PDBx:date_original>
         <PDBx:mod_type>0</PDBx:mod_type>
         <PDBx:replaces>1YL9</PDBx:replaces>
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      <PDBx:database_PDB_rev num="2">
         <PDBx:date>2009-02-24</PDBx:date>
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         <PDBx:crystal_id>1</PDBx:crystal_id>
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      <PDBx:diffrn_radiation diffrn_id="1">
         <PDBx:pdbx_diffrn_protocol>SINGLE WAVELENGTH</PDBx:pdbx_diffrn_protocol>
         <PDBx:pdbx_monochromatic_or_laue_m_l>M</PDBx:pdbx_monochromatic_or_laue_m_l>
         <PDBx:pdbx_scattering_type>x-ray</PDBx:pdbx_scattering_type>
         <PDBx:wavelength_id>1</PDBx:wavelength_id>
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         <PDBx:wavelength xsi:nil="true" />
         <PDBx:wt>1.0</PDBx:wt>
      </PDBx:diffrn_radiation_wavelength>
   </PDBx:diffrn_radiation_wavelengthCategory>
   <PDBx:entityCategory>
      <PDBx:entity id="1">
         <PDBx:formula_weight>1052.248</PDBx:formula_weight>
         <PDBx:pdbx_description>[Tyr3]Octreotate</PDBx:pdbx_description>
         <PDBx:pdbx_fragment>Somatostatin Analogue</PDBx:pdbx_fragment>
         <PDBx:pdbx_number_of_molecules>1</PDBx:pdbx_number_of_molecules>
         <PDBx:src_method>syn</PDBx:src_method>
         <PDBx:type>polymer</PDBx:type>
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      <PDBx:entity id="2">
         <PDBx:formula_weight>188.272</PDBx:formula_weight>
         <PDBx:pdbx_description>3-[(2-AMINOETHYL)AMINO]-2-{[(2-AMINOETHYL)AMINO]METHYL}PROPANAL</PDBx:pdbx_description>
         <PDBx:pdbx_number_of_molecules>1</PDBx:pdbx_number_of_molecules>
         <PDBx:src_method>syn</PDBx:src_method>
         <PDBx:type>non-polymer</PDBx:type>
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      <PDBx:entity_keywords entity_id="1">
      </PDBx:entity_keywords>
      <PDBx:entity_keywords entity_id="2">
      </PDBx:entity_keywords>
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      <PDBx:entity_poly entity_id="1">
         <PDBx:nstd_linkage>no</PDBx:nstd_linkage>
         <PDBx:nstd_monomer>yes</PDBx:nstd_monomer>
         <PDBx:pdbx_seq_one_letter_code>(DPN)CY(DTR)KTCT</PDBx:pdbx_seq_one_letter_code>
         <PDBx:pdbx_seq_one_letter_code_can>XCYWKTCT</PDBx:pdbx_seq_one_letter_code_can>
         <PDBx:pdbx_strand_id>A</PDBx:pdbx_strand_id>
         <PDBx:type>polypeptide(L)</PDBx:type>
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      <PDBx:entity_poly_seq entity_id="1" mon_id="DPN" num="1">
         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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         <PDBx:hetero>n</PDBx:hetero>
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      <PDBx:pdbx_database_related content_type="unspecified" db_id="1soc" db_name="PDB">
         <PDBx:details>Sandostatin (Octreotide) peptide</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="2soc" db_name="PDB">
         <PDBx:details>Sandostatin (Octreotide) peptide</PDBx:details>
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         <PDBx:deposit_site>RCSB</PDBx:deposit_site>
         <PDBx:process_site>RCSB</PDBx:process_site>
         <PDBx:status_code>REL</PDBx:status_code>
         <PDBx:status_code_mr>REL</PDBx:status_code_mr>
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      <PDBx:pdbx_entity_nonpoly entity_id="2">
         <PDBx:comp_id>CH4</PDBx:comp_id>
         <PDBx:name>3-[(2-AMINOETHYL)AMINO]-2-{[(2-AMINOETHYL)AMINO]METHYL}PROPANAL</PDBx:name>
      </PDBx:pdbx_entity_nonpoly>
   </PDBx:pdbx_entity_nonpolyCategory>
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      <PDBx:pdbx_entity_src_syn entity_id="1">
         <PDBx:details>Synthetic peptide with a tetramine chelator attached at the N-terminal</PDBx:details>
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      <PDBx:pdbx_nmr_details entry_id="1YL9">
         <PDBx:text>This structure was determined using standard 2D homonuclear techniques</PDBx:text>
      </PDBx:pdbx_nmr_details>
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      <PDBx:pdbx_nmr_ensemble entry_id="1YL9">
         <PDBx:conformer_selection_criteria>target function</PDBx:conformer_selection_criteria>
         <PDBx:conformers_calculated_total_number>400</PDBx:conformers_calculated_total_number>
         <PDBx:conformers_submitted_total_number>21</PDBx:conformers_submitted_total_number>
      </PDBx:pdbx_nmr_ensemble>
   </PDBx:pdbx_nmr_ensembleCategory>
   <PDBx:pdbx_nmr_exptlCategory>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="1" solution_id="1">
         <PDBx:type>2D NOESY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="2" solution_id="1">
         <PDBx:type>2D TOCSY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
   </PDBx:pdbx_nmr_exptlCategory>
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      <PDBx:pdbx_nmr_exptl_sample_conditions conditions_id="1">
         <PDBx:pressure>ambient</PDBx:pressure>
         <PDBx:temperature>298</PDBx:temperature>
      </PDBx:pdbx_nmr_exptl_sample_conditions>
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      <PDBx:pdbx_nmr_refine entry_id="1YL9">
         <PDBx:details>The models are calculated using 155 NOE-derived constraints,  from NOESY spectra acquired using 400 ms of mixing time</PDBx:details>
         <PDBx:method>simulated annealing, torsion angle dynamics</PDBx:method>
      </PDBx:pdbx_nmr_refine>
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      <PDBx:pdbx_nmr_representative entry_id="1YL9">
         <PDBx:conformer_id>1</PDBx:conformer_id>
         <PDBx:selection_criteria>minimized average structure</PDBx:selection_criteria>
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      <PDBx:pdbx_nmr_sample_details solution_id="1">
         <PDBx:contents>2-3mM peptide; DMSO</PDBx:contents>
         <PDBx:solvent_system>DMSO-d6</PDBx:solvent_system>
      </PDBx:pdbx_nmr_sample_details>
   </PDBx:pdbx_nmr_sample_detailsCategory>
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      <PDBx:pdbx_nmr_software ordinal="1">
         <PDBx:authors>Bruker</PDBx:authors>
         <PDBx:classification>collection</PDBx:classification>
         <PDBx:name>XWINNMR</PDBx:name>
         <PDBx:version>2.6</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="2">
         <PDBx:authors>Eccles, C.; Guntert, P.; Billeter, M.; Wuthrich, K.</PDBx:authors>
         <PDBx:classification>data analysis</PDBx:classification>
         <PDBx:name>XEASY</PDBx:name>
         <PDBx:version>1.3</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="3">
         <PDBx:authors>Gunthert, P.; Mumenthaler, C.; Wuthrich, K.</PDBx:authors>
         <PDBx:classification>structure solution</PDBx:classification>
         <PDBx:name>DYANA</PDBx:name>
         <PDBx:version>1.5</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="4">
         <PDBx:authors>Pearlman, D.A.; Case, D.A.; Caldwell, J.W.; Ross, W.S.; Cheatham, T.E.; Ferguson, D.M.; Seibel, G.L.; Singh, U.C.; Weiner, P.K.; Kollman, P.A.</PDBx:authors>
         <PDBx:classification>refinement</PDBx:classification>
         <PDBx:name>AMBER</PDBx:name>
         <PDBx:version>5.0</PDBx:version>
      </PDBx:pdbx_nmr_software>
   </PDBx:pdbx_nmr_softwareCategory>
   <PDBx:pdbx_nmr_spectrometerCategory>
      <PDBx:pdbx_nmr_spectrometer spectrometer_id="1">
         <PDBx:field_strength>400</PDBx:field_strength>
         <PDBx:manufacturer>Bruker</PDBx:manufacturer>
         <PDBx:model>DPX</PDBx:model>
      </PDBx:pdbx_nmr_spectrometer>
   </PDBx:pdbx_nmr_spectrometerCategory>
   <PDBx:pdbx_nonpoly_schemeCategory>
      <PDBx:pdbx_nonpoly_scheme asym_id="B" ndb_seq_num="1">
         <PDBx:auth_mon_id>CH4</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>0</PDBx:auth_seq_num>
         <PDBx:entity_id>2</PDBx:entity_id>
         <PDBx:mon_id>CH4</PDBx:mon_id>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>CH4</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>0</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_nonpoly_scheme>
   </PDBx:pdbx_nonpoly_schemeCategory>
   <PDBx:pdbx_poly_seq_schemeCategory>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="DPN" seq_id="1">
         <PDBx:auth_mon_id>DPN</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>2</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>1</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>DPN</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>2</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="CYS" seq_id="2">
         <PDBx:auth_mon_id>CYS</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>3</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>2</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>CYS</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>3</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="TYR" seq_id="3">
         <PDBx:auth_mon_id>TYR</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>4</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>3</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>TYR</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>4</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="DTR" seq_id="4">
         <PDBx:auth_mon_id>DTR</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>5</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>4</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>DTR</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>5</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="LYS" seq_id="5">
         <PDBx:auth_mon_id>LYS</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>6</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>5</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>LYS</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>6</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="THR" seq_id="6">
         <PDBx:auth_mon_id>THR</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>7</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>6</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>THR</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>7</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="CYS" seq_id="7">
         <PDBx:auth_mon_id>CYS</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>8</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>7</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>CYS</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>8</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="THR" seq_id="8">
         <PDBx:auth_mon_id>THR</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>9</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>8</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>THR</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>9</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
   </PDBx:pdbx_poly_seq_schemeCategory>
   <PDBx:pdbx_prerelease_seqCategory>
      <PDBx:pdbx_prerelease_seq entity_id="1">
         <PDBx:seq_one_letter_code>(DPN)CY(DTR)KTCT</PDBx:seq_one_letter_code>
      </PDBx:pdbx_prerelease_seq>
   </PDBx:pdbx_prerelease_seqCategory>
   <PDBx:pdbx_struct_assemblyCategory>
      <PDBx:pdbx_struct_assembly id="1">
         <PDBx:details>author_defined_assembly</PDBx:details>
         <PDBx:oligomeric_count>1</PDBx:oligomeric_count>
         <PDBx:oligomeric_details>monomeric</PDBx:oligomeric_details>
      </PDBx:pdbx_struct_assembly>
   </PDBx:pdbx_struct_assemblyCategory>
   <PDBx:pdbx_struct_assembly_genCategory>
      <PDBx:pdbx_struct_assembly_gen assembly_id="1" asym_id_list="A,B" oper_expression="1"></PDBx:pdbx_struct_assembly_gen>
   </PDBx:pdbx_struct_assembly_genCategory>
   <PDBx:pdbx_struct_mod_residueCategory>
      <PDBx:pdbx_struct_mod_residue id="1">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:details>D-TRYPTOPHAN</PDBx:details>
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_comp_id>DTR</PDBx:label_comp_id>
         <PDBx:label_seq_id>4</PDBx:label_seq_id>
         <PDBx:parent_comp_id>TRP</PDBx:parent_comp_id>
      </PDBx:pdbx_struct_mod_residue>
   </PDBx:pdbx_struct_mod_residueCategory>
   <PDBx:pdbx_struct_oper_listCategory>
      <PDBx:pdbx_struct_oper_list id="1">
         <PDBx:matrix11>1.0000000000</PDBx:matrix11>
         <PDBx:matrix12>0.0000000000</PDBx:matrix12>
         <PDBx:matrix13>0.0000000000</PDBx:matrix13>
         <PDBx:matrix21>0.0000000000</PDBx:matrix21>
         <PDBx:matrix22>1.0000000000</PDBx:matrix22>
         <PDBx:matrix23>0.0000000000</PDBx:matrix23>
         <PDBx:matrix31>0.0000000000</PDBx:matrix31>
         <PDBx:matrix32>0.0000000000</PDBx:matrix32>
         <PDBx:matrix33>1.0000000000</PDBx:matrix33>
         <PDBx:name>1_555</PDBx:name>
         <PDBx:symmetry_operation>x,y,z</PDBx:symmetry_operation>
         <PDBx:type>identity operation</PDBx:type>
         <PDBx:vector1>0.0000000000</PDBx:vector1>
         <PDBx:vector2>0.0000000000</PDBx:vector2>
         <PDBx:vector3>0.0000000000</PDBx:vector3>
      </PDBx:pdbx_struct_oper_list>
   </PDBx:pdbx_struct_oper_listCategory>
   <PDBx:pdbx_unobs_or_zero_occ_atomsCategory>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="1">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="2">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="3">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="4">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="5">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="6">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="7">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="8">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="9">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="10">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="11">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="12">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="13">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="14">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="15">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="16">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="17">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>HN2</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>Y</PDBx:polymer_flag>
      </PDBx:pdbx_unobs_or_zero_occ_atoms>
      <PDBx:pdbx_unobs_or_zero_occ_atoms id="18">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_atom_id>H</PDBx:auth_atom_id>
         <PDBx:auth_comp_id>CH4</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>0</PDBx:auth_seq_id>
         <PDBx:occupancy_flag>1</PDBx:occupancy_flag>
         <PDBx:polymer_flag>N</PDBx:polymer_flag>
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         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-106.97</PDBx:phi>
         <PDBx:psi>44.91</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="15">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>59.60</PDBx:phi>
         <PDBx:psi>17.48</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="16">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>39.99</PDBx:phi>
         <PDBx:psi>60.09</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="17">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-109.72</PDBx:phi>
         <PDBx:psi>43.84</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="18">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>23.70</PDBx:phi>
         <PDBx:psi>69.17</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="19">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-112.12</PDBx:phi>
         <PDBx:psi>67.04</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="20">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>58.67</PDBx:phi>
         <PDBx:psi>16.61</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="21">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>34.85</PDBx:phi>
         <PDBx:psi>64.94</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="22">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-112.41</PDBx:phi>
         <PDBx:psi>69.25</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="23">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>57.79</PDBx:phi>
         <PDBx:psi>18.12</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="24">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>31.99</PDBx:phi>
         <PDBx:psi>71.99</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="25">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-111.95</PDBx:phi>
         <PDBx:psi>67.61</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="26">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>58.06</PDBx:phi>
         <PDBx:psi>18.12</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="27">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>32.28</PDBx:phi>
         <PDBx:psi>71.01</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="28">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:phi>141.31</PDBx:phi>
         <PDBx:psi>41.36</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="29">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>50.76</PDBx:phi>
         <PDBx:psi>18.69</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="30">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>31.53</PDBx:phi>
         <PDBx:psi>71.22</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="31">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:phi>137.55</PDBx:phi>
         <PDBx:psi>40.64</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="32">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>54.67</PDBx:phi>
         <PDBx:psi>14.50</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="33">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>26.21</PDBx:phi>
         <PDBx:psi>71.97</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="34">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:phi>136.79</PDBx:phi>
         <PDBx:psi>38.56</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="35">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>53.23</PDBx:phi>
         <PDBx:psi>18.34</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="36">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>33.25</PDBx:phi>
         <PDBx:psi>69.91</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="37">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-96.55</PDBx:phi>
         <PDBx:psi>44.35</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="38">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>58.01</PDBx:phi>
         <PDBx:psi>18.44</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="39">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>26.31</PDBx:phi>
         <PDBx:psi>67.35</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="40">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-110.64</PDBx:phi>
         <PDBx:psi>58.66</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="41">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>5</PDBx:auth_seq_id>
         <PDBx:phi>137.65</PDBx:phi>
         <PDBx:psi>38.00</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="42">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>55.60</PDBx:phi>
         <PDBx:psi>18.89</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="43">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>32.72</PDBx:phi>
         <PDBx:psi>72.07</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="44">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-118.02</PDBx:phi>
         <PDBx:psi>75.80</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="45">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>33.85</PDBx:phi>
         <PDBx:psi>65.47</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="46">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-114.01</PDBx:phi>
         <PDBx:psi>74.29</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="47">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>54.43</PDBx:phi>
         <PDBx:psi>19.59</PDBx:psi>
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      <PDBx:pdbx_validate_torsion id="48">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>35.84</PDBx:phi>
         <PDBx:psi>61.69</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="49">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>41.98</PDBx:phi>
         <PDBx:psi>27.88</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="50">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>25.52</PDBx:phi>
         <PDBx:psi>68.58</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="51">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TYR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>-100.02</PDBx:phi>
         <PDBx:psi>79.63</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="52">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>59.17</PDBx:phi>
         <PDBx:psi>16.82</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="53">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>31.54</PDBx:phi>
         <PDBx:psi>71.85</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="54">
         <PDBx:PDB_model_num>21</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>43.04</PDBx:phi>
         <PDBx:psi>25.25</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="55">
         <PDBx:PDB_model_num>21</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>LYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>57.34</PDBx:phi>
         <PDBx:psi>18.30</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="56">
         <PDBx:PDB_model_num>21</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:phi>38.05</PDBx:phi>
         <PDBx:psi>70.06</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
   </PDBx:pdbx_validate_torsionCategory>
   <PDBx:pdbx_versionCategory>
      <PDBx:pdbx_version entry_id="1YL9" major_version="3" minor_version="2" revision_type="Version format compliance">
         <PDBx:details>compliance with PDB format V.3.15</PDBx:details>
         <PDBx:revision_date>2008-04-30</PDBx:revision_date>
      </PDBx:pdbx_version>
      <PDBx:pdbx_version entry_id="1YL9" major_version="4" minor_version="0000" revision_type="Version format compliance">
         <PDBx:details>compliance with PDB Exchange Dictionary V4</PDBx:details>
         <PDBx:revision_date>2011-07-13</PDBx:revision_date>
      </PDBx:pdbx_version>
   </PDBx:pdbx_versionCategory>
   <PDBx:structCategory>
      <PDBx:struct entry_id="1YL9">
         <PDBx:pdbx_descriptor>[Tyr3]Octreotate</PDBx:pdbx_descriptor>
         <PDBx:pdbx_model_type_details>minimized average</PDBx:pdbx_model_type_details>
         <PDBx:title>3D Solution Structure of [Tyr3]Octreotate derivatives in DMSO</PDBx:title>
      </PDBx:struct>
   </PDBx:structCategory>
   <PDBx:struct_asymCategory>
      <PDBx:struct_asym id="A">
         <PDBx:entity_id>1</PDBx:entity_id>
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
      </PDBx:struct_asym>
      <PDBx:struct_asym id="B">
         <PDBx:entity_id>2</PDBx:entity_id>
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
      </PDBx:struct_asym>
   </PDBx:struct_asymCategory>
   <PDBx:struct_biolCategory>
      <PDBx:struct_biol id="1"></PDBx:struct_biol>
   </PDBx:struct_biolCategory>
   <PDBx:struct_connCategory>
      <PDBx:struct_conn id="disulf1">
         <PDBx:conn_type_id>disulf</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>2.052</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>CYS</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>3</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>SG</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>CYS</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>2</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>CYS</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>8</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>SG</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>CYS</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>7</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale1">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.336</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>DPN</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>2</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>N</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>DPN</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>1</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>CH4</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>0</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>B</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>C</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>CH4</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id xsi:nil="true" />
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale2">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.330</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>DPN</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>2</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>DPN</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>1</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>CYS</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>3</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>CYS</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>2</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale3">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.327</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>TYR</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>4</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>TYR</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>3</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>DTR</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>5</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>DTR</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>4</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale4">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.338</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>DTR</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>5</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>DTR</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>4</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>LYS</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>6</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>LYS</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>5</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
   </PDBx:struct_connCategory>
   <PDBx:struct_conn_typeCategory>
      <PDBx:struct_conn_type id="disulf">
      </PDBx:struct_conn_type>
      <PDBx:struct_conn_type id="covale">
      </PDBx:struct_conn_type>
   </PDBx:struct_conn_typeCategory>
   <PDBx:struct_keywordsCategory>
      <PDBx:struct_keywords entry_id="1YL9">
         <PDBx:pdbx_keywords>NEUROPEPTIDE</PDBx:pdbx_keywords>
         <PDBx:text>Somatostatin Analogues, Sandostatin, [Tyr3]Octreotate, Demotate, NMR conformational analysis, NEUROPEPTIDE</PDBx:text>
      </PDBx:struct_keywords>
   </PDBx:struct_keywordsCategory>
   <PDBx:struct_refCategory>
      <PDBx:struct_ref id="1">
         <PDBx:biol_id xsi:nil="true" />
         <PDBx:db_code>1YL9</PDBx:db_code>
         <PDBx:db_name>PDB</PDBx:db_name>
         <PDBx:entity_id>1</PDBx:entity_id>
         <PDBx:pdbx_db_accession>1YL9</PDBx:pdbx_db_accession>
      </PDBx:struct_ref>
   </PDBx:struct_refCategory>
   <PDBx:struct_ref_seqCategory>
      <PDBx:struct_ref_seq align_id="1">
         <PDBx:db_align_beg>2</PDBx:db_align_beg>
         <PDBx:db_align_end>9</PDBx:db_align_end>
         <PDBx:pdbx_PDB_id_code>1YL9</PDBx:pdbx_PDB_id_code>
         <PDBx:pdbx_auth_seq_align_beg>2</PDBx:pdbx_auth_seq_align_beg>
         <PDBx:pdbx_auth_seq_align_end>9</PDBx:pdbx_auth_seq_align_end>
         <PDBx:pdbx_db_accession>1YL9</PDBx:pdbx_db_accession>
         <PDBx:pdbx_strand_id>A</PDBx:pdbx_strand_id>
         <PDBx:ref_id>1</PDBx:ref_id>
         <PDBx:seq_align_beg>1</PDBx:seq_align_beg>
         <PDBx:seq_align_end>8</PDBx:seq_align_end>
      </PDBx:struct_ref_seq>
   </PDBx:struct_ref_seqCategory>
   <PDBx:struct_siteCategory>
      <PDBx:struct_site id="AC1">
         <PDBx:details>BINDING SITE FOR RESIDUE CH4 A 0</PDBx:details>
         <PDBx:pdbx_evidence_code>SOFTWARE</PDBx:pdbx_evidence_code>
      </PDBx:struct_site>
   </PDBx:struct_siteCategory>
   <PDBx:struct_site_genCategory>
      <PDBx:struct_site_gen id="1" site_id="AC1">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DPN</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:label_alt_id xsi:nil="true" />
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_atom_id xsi:nil="true" />
         <PDBx:label_comp_id>DPN</PDBx:label_comp_id>
         <PDBx:label_seq_id>1</PDBx:label_seq_id>
         <PDBx:pdbx_num_res>3</PDBx:pdbx_num_res>
         <PDBx:symmetry>1_555</PDBx:symmetry>
      </PDBx:struct_site_gen>
      <PDBx:struct_site_gen id="2" site_id="AC1">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:label_alt_id xsi:nil="true" />
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_atom_id xsi:nil="true" />
         <PDBx:label_comp_id>CYS</PDBx:label_comp_id>
         <PDBx:label_seq_id>2</PDBx:label_seq_id>
         <PDBx:pdbx_num_res>3</PDBx:pdbx_num_res>
         <PDBx:symmetry>1_555</PDBx:symmetry>
      </PDBx:struct_site_gen>
      <PDBx:struct_site_gen id="3" site_id="AC1">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>THR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>9</PDBx:auth_seq_id>
         <PDBx:label_alt_id xsi:nil="true" />
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_atom_id xsi:nil="true" />
         <PDBx:label_comp_id>THR</PDBx:label_comp_id>
         <PDBx:label_seq_id>8</PDBx:label_seq_id>
         <PDBx:pdbx_num_res>3</PDBx:pdbx_num_res>
         <PDBx:symmetry>1_555</PDBx:symmetry>
      </PDBx:struct_site_gen>
   </PDBx:struct_site_genCategory>
   <PDBx:symmetryCategory>
      <PDBx:symmetry entry_id="1YL9">
         <PDBx:space_group_name_H-M>P 1</PDBx:space_group_name_H-M>
      </PDBx:symmetry>
   </PDBx:symmetryCategory>
</PDBx:datablock>
